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Fuel gas

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Blue flame of fuel gas burners
Blue flame of fuel gas burners

Fuel gas is any one of a number of fuels that under ordinary conditions are gaseous. Most fuel gases are composed of hydrocarbons (such as methane or propane), hydrogen, carbon monoxide, or mixtures thereof. Such gases are sources energy that can be readily transmitted and distributed through pipes.

Fuel gas is contrasted with liquid fuels and from solid fuels, although some fuel gases are liquefied for storage or transport (for example, autogas). While their gaseous nature has advantages, avoiding the difficulty of transporting solid fuel and the dangers of spillage inherent in liquid fuels, it also has limitation. It is possible for a fuel gas to be undetected and cause gas explosion. For this reason, odorizers are added to most fuel gases. The most common type of fuel gas in current use is natural gas.

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Fuel

Fuel

A fuel is any material that can be made to react with other substances so that it releases energy as thermal energy or to be used for work. The concept was originally applied solely to those materials capable of releasing chemical energy but has since also been applied to other sources of heat energy, such as nuclear energy.

Gas

Gas

Gas is one of the four fundamental states of matter. The others are solid, liquid, and plasma.

Hydrocarbon

Hydrocarbon

In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic; their odor is usually faint, and may be similar to that of gasoline or lighter fluid. They occur in a diverse range of molecular structures and phases: they can be gases, liquids, low melting solids or polymers.

Methane

Methane

Methane is a chemical compound with the chemical formula CH4. It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on Earth makes it an economically attractive fuel, although capturing and storing it poses technical challenges due to its gaseous state under normal conditions for temperature and pressure.

Hydrogen

Hydrogen

Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula H2. It is colorless, odorless, tasteless, non-toxic, and highly combustible. Hydrogen is the most abundant chemical substance in the universe, constituting roughly 75% of all normal matter. Stars such as the Sun are mainly composed of hydrogen in the plasma state. Most of the hydrogen on Earth exists in molecular forms such as water and organic compounds. For the most common isotope of hydrogen each atom has one proton, one electron, and no neutrons.

Carbon monoxide

Carbon monoxide

Carbon monoxide is a poisonous, flammable gas that is colorless, odorless, tasteless, and slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simplest carbon oxide. In coordination complexes the carbon monoxide ligand is called carbonyl. It is a key ingredient in many processes in industrial chemistry.

Energy

Energy

In physics, energy is the quantitative property that is transferred to a body or to a physical system, recognizable in the performance of work and in the form of heat and light. Energy is a conserved quantity—the law of conservation of energy states that energy can be converted in form, but not created or destroyed. The unit of measurement for energy in the International System of Units (SI) is the joule (J).

Liquid fuel

Liquid fuel

Liquid fuels are combustible or energy-generating molecules that can be harnessed to create mechanical energy, usually producing kinetic energy; they also must take the shape of their container. It is the fumes of liquid fuels that are flammable instead of the fluid. Most liquid fuels in widespread use are derived from fossil fuels; however, there are several types, such as hydrogen fuel, ethanol, and biodiesel, which are also categorized as a liquid fuel. Many liquid fuels play a primary role in transportation and the economy.

Liquefaction of gases

Liquefaction of gases

Liquefaction of gases is physical conversion of a gas into a liquid state (condensation). The liquefaction of gases is a complicated process that uses various compressions and expansions to achieve high pressures and very low temperatures, using, for example, turboexpanders.

Autogas

Autogas

Autogas or LPG is liquefied petroleum gas (LPG) used as a fuel in internal combustion engines in vehicles as well as in stationary applications such as generators. It is a mixture of propane and butane.

Gas explosion

Gas explosion

A gas explosion is an accident resulting from ignition of a mixture of air and flammable gas, typically from a gas leak. In household accidents, the principal explosive gases are those used for heating or cooking purposes such as natural gas, methane, propane, butane. In industrial explosions many other gases, like hydrogen, as well as evaporated (gaseous) gasoline or ethanol play an important role. Industrial gas explosions can be prevented with the use of intrinsic safety barriers to prevent ignition.

Natural gas

Natural gas

Natural gas is a naturally occurring mixture of gaseous hydrocarbons consisting primarily of methane in addition to various smaller amounts of other higher alkanes. Low levels of trace gases like carbon dioxide, nitrogen, hydrogen sulfide, and helium are also usually present. Natural gas is colorless and odorless, so odorizers such as mercaptan are commonly added to natural gas supplies for safety so that leaks can be readily detected.

Types

19th-century style gas lights in New Orleans
19th-century style gas lights in New Orleans

There are two broad classes of fuel gases, based not on their chemical composition, but their source and the way they are produced: those found naturally, and those manufactured from other materials.

Manufactured fuel gas

Manufactured fuel gases are those produced by chemical transformations of solids, liquids, or other gases. When obtained from solids, the conversion is referred to as gasification and the facility is known as a gasworks.

Manufactured fuel gases include:[1]

Well or mine extracted fuel gases

In the 20th century, natural gas, composed primarily of methane, became the dominant source of fuel gas, as instead of having to be manufactured in various processes, it could be extracted from deposits in the earth. Natural gas may be combined with hydrogen to form a mixture known as HCNG.

Additional fuel gases obtained from natural gas or petroleum:

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Gasification

Gasification

Gasification is a process that converts biomass- or fossil fuel-based carbonaceous materials into gases, including as the largest fractions: nitrogen (N2), carbon monoxide (CO), hydrogen (H2), and carbon dioxide (CO2). This is achieved by reacting the feedstock material at high temperatures (typically >700 °C), without combustion, via controlling the amount of oxygen and/or steam present in the reaction. The resulting gas mixture is called syngas (from synthesis gas) or producer gas and is itself a fuel due to the flammability of the H2 and CO of which the gas is largely composed. Power can be derived from the subsequent combustion of the resultant gas, and is considered to be a source of renewable energy if the gasified compounds were obtained from biomass feedstock.

Gasworks

Gasworks

A gasworks or gas house is an industrial plant for the production of flammable gas. Many of these have been made redundant in the developed world by the use of natural gas, though they are still used for storage space.

Coal gas

Coal gas

Coal gas is a flammable gaseous fuel made from coal and supplied to the user via a piped distribution system. It is produced when coal is heated strongly in the absence of air. Town gas is a more general term referring to manufactured gaseous fuels produced for sale to consumers and municipalities.

Coke (fuel)

Coke (fuel)

Coke is a grey, hard, and porous coal-based fuel with a high carbon content and few impurities, made by heating coal or oil in the absence of air—a destructive distillation process. It is an important industrial product, used mainly in iron ore smelting, but also as a fuel in stoves and forges when air pollution is a concern.

Natural gas

Natural gas

Natural gas is a naturally occurring mixture of gaseous hydrocarbons consisting primarily of methane in addition to various smaller amounts of other higher alkanes. Low levels of trace gases like carbon dioxide, nitrogen, hydrogen sulfide, and helium are also usually present. Natural gas is colorless and odorless, so odorizers such as mercaptan are commonly added to natural gas supplies for safety so that leaks can be readily detected.

Biofuel

Biofuel

Biofuel is a fuel that is produced over a short time span from biomass, rather than by the very slow natural processes involved in the formation of fossil fuels, such as oil. Biofuel can be produced from plants or from agricultural, domestic or industrial biowaste. The climate change mitigation potential of biofuel varies considerably, from emission levels comparable to fossil fuels in some scenarios to negative emissions in others. Biofuels are mostly used for transportation, but can also be used for heating and electricity. Biofuels are regarded as a renewable energy source.

Biogas

Biogas

Biogas is a mixture of gases, primarily consisting of methane, carbon dioxide and hydrogen sulphide, produced from raw materials such as agricultural waste, manure, municipal waste, plant material, sewage, green waste, wastewater, and food waste. It is a renewable energy source.

Blast furnace gas

Blast furnace gas

Blast furnace gas (BFG) is a by-product of blast furnaces that is generated when the iron ore is reduced with coke to metallic iron. It has a very low heating value, about 93 BTU/cubic foot (3.5 MJ/m3), because it consists of about 51 vol% nitrogen and 22 vol% carbon dioxide, which are not flammable. The rest amounts to around 22 vol% carbon monoxide, which has a fairly low heating value already and 5 vol% hydrogen. Per ton of steel produced via the blast furnace route, 2.5 to 3.5 ton of blast furnace gas is produced. It is commonly used as a fuel within the steel works, but it can be used in boilers and power plants equipped to burn it. It may be combined with natural gas or coke oven gas before combustion or a flame support with richer gas or oil is provided to sustain combustion. Particulate matter is removed so that it can be burned more cleanly. Blast furnace gas is sometimes flared without generating heat or electricity.

Fossil fuel

Fossil fuel

A fossil fuel is a hydrocarbon-containing material such as coal, oil, and natural gas, formed naturally in the Earth's crust from the remains of dead plants and animals that is extracted and burned as a fuel. Fossil fuels may be burned to provide heat for use directly, to power engines, or to generate electricity. Some fossil fuels are refined into derivatives such as kerosene, gasoline and propane before burning. The origin of fossil fuels is the anaerobic decomposition of buried dead organisms, containing organic molecules created by photosynthesis. The conversion from these materials to high-carbon fossil fuels typically require a geological process of millions of years.

Methane

Methane

Methane is a chemical compound with the chemical formula CH4. It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on Earth makes it an economically attractive fuel, although capturing and storing it poses technical challenges due to its gaseous state under normal conditions for temperature and pressure.

HCNG

HCNG

HCNG or H2CNG is a mixture of compressed natural gas and 4–9 percent hydrogen by energy. It may be used as a fuel gas for internal combustion engines and home appliances.

Petroleum

Petroleum

Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name petroleum covers both naturally occurring unprocessed crude oil and petroleum products that consist of refined crude oil. A fossil fuel, petroleum is formed when large quantities of dead organisms, mostly zooplankton and algae, are buried underneath sedimentary rock and subjected to both prolonged heat and pressure.

Uses

One of the earliest uses was gas lighting, which enabled the widespread adoption of streetlamps and the illumination of buildings in towns. Fuel gas was also used in gas burners, in particular the Bunsen burner used in laboratory settings. It may also be used gas heaters, camping stoves, and even to power vehicles, they have high calorific value.

Currently, fuel gases, especially syngas, are used heavily for the production of ammonia for fertilizers and for the preparation of many detergents and specialty chemicals.[1]

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Source: "Fuel gas", Wikipedia, Wikimedia Foundation, (2023, January 5th), https://en.wikipedia.org/wiki/Fuel_gas.

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References
  1. ^ a b Hiller, Heinz; Reimert, Rainer; Stönner, Hans-Martin (2011). "Gas Production, 1. Introduction". Ullmann's Encyclopedia of Industrial Chemistry. doi:10.1002/14356007.a12_169.pub3. ISBN 978-3527306732.


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