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Donald Mastick

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Donald Mastick
Donald F. Mastick Los Alamos ID.png
Los Alamos ID
Born(1920-09-01)September 1, 1920
DiedSeptember 8, 2007(2007-09-08) (aged 87)
Alma materUniversity of California, Berkeley (BS 1942, PhD 1950)
AwardsBronze Star Medal
Scientific career
FieldsChemistry
Institutions
ThesisA study of gaseous oxides at high temperatures (1950)

Donald Francis Mastick (September 1, 1920 – September 8, 2007) was an American chemist who worked at the Manhattan Project's Los Alamos Laboratory. As part of Project Alberta, he was part of the planning and preparation for the atomic bombing of Hiroshima and Nagasaki, for which he was awarded the Bronze Star Medal. He later worked for the Naval Radiological Defense Laboratory and the Atomic Energy Commission. In 1971, he founded his own interior landscape company, Foliage Plant Systems.

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Manhattan Project

Manhattan Project

The Manhattan Project was a research and development undertaking during World War II that produced the first nuclear weapons. It was led by the United States with the support of the United Kingdom and Canada. From 1942 to 1946, the project was under the direction of Major General Leslie Groves of the U.S. Army Corps of Engineers. Nuclear physicist Robert Oppenheimer was the director of the Los Alamos Laboratory that designed the actual bombs. The Army component of the project was designated the Manhattan District as its first headquarters were in Manhattan; the placename gradually superseded the official codename, Development of Substitute Materials, for the entire project. Along the way, the project absorbed its earlier British counterpart, Tube Alloys. The Manhattan Project began modestly in 1939, but grew to employ nearly 130,000 people at its peak and cost nearly US$2 billion. Over 90 percent of the cost was for building factories and to produce fissile material, with less than 10 percent for development and production of the weapons. Research and production took place at more than thirty sites across the United States, the United Kingdom, and Canada.

Project Alberta

Project Alberta

Project Alberta, also known as Project A, was a section of the Manhattan Project which assisted in delivering the first nuclear weapons in the atomic bombing of Hiroshima and Nagasaki during World War II.

Bronze Star Medal

Bronze Star Medal

The Bronze Star Medal (BSM) is a United States Armed Forces decoration awarded to members of the United States Armed Forces for either heroic achievement, heroic service, meritorious achievement, or meritorious service in a combat zone.

Naval Radiological Defense Laboratory

Naval Radiological Defense Laboratory

The United States Naval Radiological Defense Laboratory (NRDL) was an early military lab created to study the effects of radiation and nuclear weapons. The facility was based at the Hunter's Point Naval Shipyard in San Francisco, California.

United States Atomic Energy Commission

United States Atomic Energy Commission

The United States Atomic Energy Commission (AEC) was an agency of the United States government established after World War II by U.S. Congress to foster and control the peacetime development of atomic science and technology. President Harry S. Truman signed the McMahon/Atomic Energy Act on August 1, 1946, transferring the control of atomic energy from military to civilian hands, effective on January 1, 1947. This shift gave the members of the AEC complete control of the plants, laboratories, equipment, and personnel assembled during the war to produce the atomic bomb.

Early life

Donald Francis Mastick was born in St. Helena, California, the son of Spencer Mastick and his wife Frankie née Hite. He grew up in the Napa Valley. He entered the University of California, Berkeley, where he studied chemistry, graduating with his Bachelor of Science degree in 1942. He was a member of the Phi Beta Kappa and Sigma Xi honor societies.[1][2]

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St. Helena, California

St. Helena, California

St. Helena is a city in Napa County, California, United States. Located in the North Bay region of the San Francisco Bay Area, the population was 5,814 at the 2010 census.

University of California, Berkeley

University of California, Berkeley

The University of California, Berkeley is a public land-grant research university in Berkeley, California. Established in 1868 as the University of California, it is the state's first land-grant university and the founding campus of the University of California system. Its fourteen colleges and schools offer over 350 degree programs and enroll some 32,000 undergraduate and 13,000 graduate students. Berkeley ranks among the world's top universities.

Chemistry

Chemistry

Chemistry is the scientific study of the properties and behavior of matter. It is a physical science under natural sciences that covers the elements that make up matter to the compounds made of atoms, molecules and ions: their composition, structure, properties, behavior and the changes they undergo during a reaction with other substances. Chemistry also addresses the nature of chemical bonds in chemical compounds.

Bachelor of Science

Bachelor of Science

A Bachelor of Science is a bachelor's degree awarded for programs that generally last three to five years.

Phi Beta Kappa

Phi Beta Kappa

The Phi Beta Kappa Society (ΦΒΚ) is the oldest academic honor society in the United States, and the most prestigious, due in part to its long history and academic selectivity. Phi Beta Kappa aims to promote and advocate excellence in the liberal arts and sciences, and to induct the most outstanding students of arts and sciences at only select American colleges and universities. It was founded at the College of William and Mary on December 5, 1776, as the first collegiate Greek-letter fraternity and was among the earliest collegiate fraternal societies. Since its inception, 17 U.S. presidents, 40 U.S. Supreme Court justices, and 136 Nobel laureates have been inducted members.

Sigma Xi

Sigma Xi

Sigma Xi, The Scientific Research Honor Society (ΣΞ) is a highly prestigious, non-profit honor society for scientists and engineers. Sigma Xi was founded at Cornell University by a junior faculty member and a small group of graduate students in 1886, making it one of the oldest honor societies. Membership in Sigma Xi is by invitation only, where members nominate others on the basis of their research achievements or potential. Sigma Xi goals aim to honor excellence in scientific investigation and encourage cooperation among researchers in all fields of science and engineering.

Manhattan Project

By the time Mastick graduated, the United States had entered World War II. Mastick was studying radioactive carbon. He told Professor Wendell Latimer that he could not stand by while there was a war on, and that he was leaving. Latimer suggested that he instead join a secret project, which would lead to a commission in the United States Navy. He introduced him to Robert Oppenheimer, who recruited him for the Manhattan Project. Initially, Mastick's job was to draw up lists of equipment required by the chemistry laboratories at the Los Alamos Laboratory, which were then under construction.[3]

Mastick moved to Los Alamos early in 1943, where he worked in the Chemistry Division and studied the mysterious chemical properties of plutonium, a synthetic element then available only in microscopic quantities.[2] Although young, he was a member of the group that planned the laboratory's scientific program, along with Robert Wilson, Robert Serber, John Williams and Edwin McMillan.[4]

On August 1, 1944, Mastick and his laboratory partner, Arthur Wahl, were working with a vial containing 10 milligrams of plutonium chloride dissolved in an acid solution when the vial exploded. Gases had built up in the vial overnight, most likely through the dissociation of water molecules due to alpha radiation from the plutonium. Mastick tasted some of the acid in his mouth, so he knew that he had ingested some plutonium.[5] Mastick replaced the vial in its wooden container, and went to see Dr. Louis Hempelmann, the Director of the Health Group at Los Alamos. Hempelmann phoned Colonel Stafford L. Warren, the Manhattan Project's medical director, at the Clinton Engineer Works in Oak Ridge, Tennessee.[5][6]

Group photograph of Project Alberta. Mastick is in the third row from the front, on the far right.
Group photograph of Project Alberta. Mastick is in the third row from the front, on the far right.

Mastick's face was scrubbed, but his skin remained contaminated with a microgram of plutonium. Hempelmann gave him a mouthwash of trisodium citrate, which would combine with the plutonium to form a soluble liquid, and sodium bicarbonate, which would make it solid again. This removed most of the plutonium. Nonetheless, for days afterwards his breath could make the needle on an ionization chamber go off the scale, even from 6 feet (1.8 m) away.[5] Hempelmann used a stomach pump to retrieve plutonium that had been swallowed, which recovered about 60 nanograms of plutonium. Urine assays indicated that less than 1 microgram remained in his body. Some was still detectable 30 years later.[5][6]

Unable to work in the Chemistry Division any more because of the accident, Mastick suggested to Oppenheimer that he become an assistant to Commander Frederick Ashworth. Mastick initially served as Ashworth's administrative assistant, but soon became involved in the drop-testing of pumpkin bombs in the Salton Sea, Silverplate modifications to the Boeing B-29 Superfortress to carry nuclear weapons, and modifications to the casing and tail configurations of the bombs themselves. He also investigated the inadvertent dropping of Little Boy due to a faulty electrical circuit.[3][7]

Mastick was commissioned as an ensign in the United States Navy Reserve in June 1945. Five days later he headed to Tinian as part of Project Alberta. For his part in the atomic bombing of Hiroshima and Nagasaki, he was awarded the Bronze Star Medal.[3] After the war ended he participated in the Operation Crossroads nuclear tests at Bikini Atoll. He left the Navy with the rank of lieutenant (junior grade).[1]

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Manhattan Project

Manhattan Project

The Manhattan Project was a research and development undertaking during World War II that produced the first nuclear weapons. It was led by the United States with the support of the United Kingdom and Canada. From 1942 to 1946, the project was under the direction of Major General Leslie Groves of the U.S. Army Corps of Engineers. Nuclear physicist Robert Oppenheimer was the director of the Los Alamos Laboratory that designed the actual bombs. The Army component of the project was designated the Manhattan District as its first headquarters were in Manhattan; the placename gradually superseded the official codename, Development of Substitute Materials, for the entire project. Along the way, the project absorbed its earlier British counterpart, Tube Alloys. The Manhattan Project began modestly in 1939, but grew to employ nearly 130,000 people at its peak and cost nearly US$2 billion. Over 90 percent of the cost was for building factories and to produce fissile material, with less than 10 percent for development and production of the weapons. Research and production took place at more than thirty sites across the United States, the United Kingdom, and Canada.

Plutonium

Plutonium

Plutonium is a radioactive chemical element with the symbol Pu and atomic number 94. It is an actinide metal of silvery-gray appearance that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibits six allotropes and four oxidation states. It reacts with carbon, halogens, nitrogen, silicon, and hydrogen. When exposed to moist air, it forms oxides and hydrides that can expand the sample up to 70% in volume, which in turn flake off as a powder that is pyrophoric. It is radioactive and can accumulate in bones, which makes the handling of plutonium dangerous.

Robert R. Wilson

Robert R. Wilson

Robert Rathbun Wilson was an American physicist known for his work on the Manhattan Project during World War II, as a sculptor, and as an architect of the Fermi National Accelerator Laboratory (Fermilab), where he was the first director from 1967 to 1978.

Robert Serber

Robert Serber

Robert Serber was an American physicist who participated in the Manhattan Project. Serber's lectures explaining the basic principles and goals of the project were printed and supplied to all incoming scientific staff, and became known as The Los Alamos Primer. The New York Times called him “the intellectual midwife at the birth of the atomic bomb.”

John Harry Williams

John Harry Williams

John Harry Williams was a Canadian-American physicist.

Edwin McMillan

Edwin McMillan

Edwin Mattison McMillan was an American physicist credited with being the first-ever to produce a transuranium element, neptunium. For this, he shared the 1951 Nobel Prize in Chemistry with Glenn Seaborg.

Arthur Wahl

Arthur Wahl

Arthur Charles Wahl was an American chemist who, as a doctoral student of Glenn T. Seaborg at the University of California, Berkeley, first isolated plutonium in February 1941. He was a worker on the Manhattan Project in Los Alamos until 1946, when he joined Washington University in St. Louis. Beginning in 1952, he was the Henry V. Farr Professor of Radiochemistry; he received the American Chemical Society Award in Nuclear Chemistry in 1966 and retired in 1983. He moved back to Los Alamos in 1991 and continued his scientific writing until 2005. He died in 2006 of Parkinson's disease and pneumonia.

Plutonium(III) chloride

Plutonium(III) chloride

Plutonium(III) chloride is a chemical compound with the formula PuCl3. This ionic plutonium salt can be prepared by reacting the metal with hydrochloric acid.

Dissociation (chemistry)

Dissociation (chemistry)

Dissociation in chemistry is a general process in which molecules (or ionic compounds such as salts, or complexes) separate or split into other things such as atoms, ions, or radicals, usually in a reversible manner. For instance, when an acid dissolves in water, a covalent bond between an electronegative atom and a hydrogen atom is broken by heterolytic fission, which gives a proton (H+) and a negative ion. Dissociation is the opposite of association or recombination.

Louis Hempelmann

Louis Hempelmann

Louis Henry Hempelmann Jr, was an American physician who was the director of the Health Group at the Manhattan Project's Los Alamos Laboratory during World War II. After the war he was involved in research into radiology. A paper he published in the New England Journal of Medicine in 1949 warned of the dangers of using fluoroscopes to measure the size of children's feet.

Clinton Engineer Works

Clinton Engineer Works

The Clinton Engineer Works (CEW) was the production installation of the Manhattan Project that during World War II produced the enriched uranium used in the 1945 bombing of Hiroshima, as well as the first examples of reactor-produced plutonium. It consisted of production facilities arranged at three major sites, various utilities including a power plant, and the town of Oak Ridge. It was in East Tennessee, about 18 miles (29 km) west of Knoxville, and was named after the town of Clinton, eight miles (13 km) to the north. The production facilities were mainly in Roane County, and the northern part of the site was in Anderson County. The Manhattan District Engineer, Kenneth Nichols, moved the Manhattan District headquarters from Manhattan to Oak Ridge in August 1943. During the war, Clinton's advanced research was managed for the government by the University of Chicago.

Oak Ridge, Tennessee

Oak Ridge, Tennessee

Oak Ridge is a city in Anderson and Roane counties in the eastern part of the U.S. state of Tennessee, about 25 miles (40 km) west of downtown Knoxville. Oak Ridge's population was 31,402 at the 2020 census. It is part of the Knoxville Metropolitan Area. Oak Ridge's nicknames include the Atomic City, the Secret City, the Ridge, the Town the Atomic Bomb Built, and the City Behind the Fence.

Post-war

Mastick returned to the University of California, where he earned his PhD in 1950, writing his thesis on A study of gaseous oxides at high temperatures.[8] He became the head of the Radiochemical Research section at the Naval Radiological Defense Laboratory San Francisco.[1] In 1951 he joined the Atomic Energy Commission, as a scientific advisor and the manager of the Division of Military Applications.[2] He then became Vice President and Director of Precision Technology at General Precision Equipment. In 1957, he joined Stauffer Chemical as its Director of Research. He married Irene Pietrusiak, and they had a daughter, Patricia. In 1971, they started an interior landscape company, Foliage Plant Systems. Initially located in Saddle River, New Jersey, the business subsequently expanded into seven states, and earned accolades including one presented by Nancy Reagan at the White House in Washington, D.C.[1][9]

Mastick died in Santa Barbara, California, on September 8, 2007.[1]

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Naval Radiological Defense Laboratory

Naval Radiological Defense Laboratory

The United States Naval Radiological Defense Laboratory (NRDL) was an early military lab created to study the effects of radiation and nuclear weapons. The facility was based at the Hunter's Point Naval Shipyard in San Francisco, California.

United States Atomic Energy Commission

United States Atomic Energy Commission

The United States Atomic Energy Commission (AEC) was an agency of the United States government established after World War II by U.S. Congress to foster and control the peacetime development of atomic science and technology. President Harry S. Truman signed the McMahon/Atomic Energy Act on August 1, 1946, transferring the control of atomic energy from military to civilian hands, effective on January 1, 1947. This shift gave the members of the AEC complete control of the plants, laboratories, equipment, and personnel assembled during the war to produce the atomic bomb.

General Precision Equipment

General Precision Equipment

The General Precision Equipment Corporation was a major manufacturing company involved in the defense and space industries as well educational products and control devices for consumer goods. General Precision, Inc., was the principal operating subsidiary of General Precision Equipment Corp. headquartered in Tarrytown, New York.

Stauffer Chemical

Stauffer Chemical

Stauffer Chemical Company was an American chemical company which manufactured herbicides and pesticides for various agricultural crops. It was acquired by Imperial Chemical Industries from Chesebrough-Pond's Inc. in 1987. In 1987, Stauffer's head office was in Westport, Connecticut. Late that year, Imperial sold Stauffer's basic chemicals business to Rhône-Poulenc S.A.

Saddle River, New Jersey

Saddle River, New Jersey

Saddle River is a borough in Bergen County, in the U.S. state of New Jersey. It is a suburb of New York City, located just over 25 miles (40 km) northwest of Manhattan. The town is known for its natural fields, farmland, forests, and rivers, and has a bucolic atmosphere, due in part to a minimum zoning requirement of 2 acres (0.81 ha) for homes. The borough contains both stately historic homes and estates, as well as newer mansions. It is popular among residents seeking spacious properties in a countryside-like setting, while also having proximity to New York City.

Nancy Reagan

Nancy Reagan

Nancy Davis Reagan was an American film actress and the first lady of the United States from 1981 to 1989 as the second wife of president Ronald Reagan.

White House

White House

The White House is the official residence and workplace of the president of the United States. It is located at 1600 Pennsylvania Avenue NW in Washington, D.C., and has been the residence of every U.S. president since John Adams in 1800 when the national capital was moved from Philadelphia to Washington, D.C. The term "White House" is often used as metonymy for the president and his advisers.

Washington, D.C.

Washington, D.C.

Washington, D.C., formally the District of Columbia and commonly known as Washington or D.C., is the capital city and federal district of the United States. The city is located on the east bank of the Potomac River, which forms its southwestern border with Virginia, and borders Maryland to its north and east. The city was named for George Washington, a Founding Father, commanding general of the Continental Army in the American Revolutionary War, and the first president of the United States, and the district is named for Columbia, the female personification of the nation.

Santa Barbara, California

Santa Barbara, California

Santa Barbara is a coastal city in Santa Barbara County, California, of which it is also the county seat. Situated on a south-facing section of coastline, the longest such section on the West Coast of the United States, the city lies between the steeply rising Santa Ynez Mountains and the Pacific Ocean. Santa Barbara's climate is often described as Mediterranean, and the city has been dubbed "The American Riviera". According to the 2020 U.S. Census, the city's population was 88,665.

Source: "Donald Mastick", Wikipedia, Wikimedia Foundation, (2022, July 9th), https://en.wikipedia.org/wiki/Donald_Mastick.

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Notes
  1. ^ a b c d e "Donald Mastick Obituary (2007)". The Record/Herald News. September 16, 2007. Retrieved August 12, 2021 – via legacy.com.
  2. ^ a b c "Donald F. Mastick". Atomic Heritage Foundation. Retrieved August 12, 2021.
  3. ^ a b c Krauss & Krauss 2005, p. 133.
  4. ^ Hoddeson et al. 1993, p. 68.
  5. ^ a b c d Welsome 1999, pp. 15–19.
  6. ^ a b Moss & Eckhard 1995, p. 190.
  7. ^ Dvorak 2013, pp. 9, 16.
  8. ^ Mastick, Donald Francis (1950). "A study of gaseous oxides at high temperatures". Retrieved August 13, 2021.
  9. ^ "Victoria Pietrusiak". Welch-Ryce-Haider Funeral Chapels. Retrieved August 12, 2021.
References
  • Dvorak, Darrell F. (Winter 2013). "The First Atomic Bomb Mission: Trinity B-29 Operations Three Weeks Before Hiroshima". Air Power History. 60 (4): 4–17. ISSN 1044-016X.
  • Hoddeson, Lillian; Henriksen, Paul W.; Meade, Roger A.; Westfall, Catherine L. (1993). Critical Assembly: A Technical History of Los Alamos During the Oppenheimer Years, 1943–1945. New York: Cambridge University Press. p. 68. ISBN 0-521-44132-3. OCLC 26764320.
  • Krauss, Robert; Krauss, Amelia, eds. (2005). The 509th Remembered: A History of the 509th Composite Group as Told by the Veterans Themselves, 509th Anniversary Reunion, Wichita, Kansas October 7–10, 2004. Buchanan, Michigan: 509th Press. ISBN 978-0-923568-66-5. OCLC 59148135.
  • Moss, William; Eckhard, Roger (1995). "The Human Plutonium Injection Experiments". Los Alamos Science (23): 177–233. ISSN 0273-7116. Retrieved August 13, 2021.
  • Welsome, Eileen (1999). The Plutonium Files: America's Secret Medical Experiments in the Cold War. New York: The Dial Press. ISBN 0-385-31402-7. OCLC 537755781.

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