Chemical warfare

Chemical warfare is different from the use of conventional weapons or nuclear weapons because the destructive effects of chemical weapons are not primarily due to any explosive force. The offensive use of living organisms (such as anthrax) is considered biological warfare rather than chemical warfare; however, the use of nonliving toxic products produced by living organisms (e.g. toxins such as botulinum toxin, ricin, and saxitoxin) is considered chemical warfare under the provisions of the Chemical Weapons Convention (CWC). Under this convention, any toxic chemical, regardless of its origin, is considered a chemical weapon unless it is used for purposes that are not prohibited (an important legal definition known as the General Purpose Criterion).^[2]

About 70 different chemicals have been used or were stockpiled as chemical warfare agents during the 20th century. The entire class, known as Lethal Unitary Chemical Agents and Munitions, have been scheduled for elimination by the CWC.^[3]

Under the convention, chemicals that are toxic enough to be used as chemical weapons, or that may be used to manufacture such chemicals, are divided into three groups according to their purpose and treatment:

• Schedule 1 – Have few, if any, legitimate uses. These may only be produced or used for research, medical, pharmaceutical or protective purposes (i.e. testing of chemical weapons sensors and protective clothing). Examples include nerve agents, ricin, lewisite and mustard gas. Any production over 100 grams (3.5 oz) must be reported to the Organisation for the Prohibition of Chemical Weapons (OPCW) and a country can have a stockpile of no more than one tonne of these chemicals.
• Schedule 2 – Have no large-scale industrial uses, but may have legitimate small-scale uses. Examples include dimethyl methylphosphonate, a precursor to sarin also used as a flame retardant, and thiodiglycol, a precursor chemical used in the manufacture of mustard gas but also widely used as a solvent in inks.
• Schedule 3 – Have legitimate large-scale industrial uses. Examples include phosgene and chloropicrin. Both have been used as chemical weapons but phosgene is an important precursor in the manufacture of plastics, and chloropicrin is used as a fumigant. The OPCW must be notified of, and may inspect, any plant producing more than 30 tons per year.

Chemical weapons are divided into three categories:^[4]

• Category 1 - based on Schedule 1 substances
• Category 2 - based on non-Schedule 1 substances
• Category 3 - devices and equipment designed to use chemical weapons, without the substances themselves

Discover more about Definition related topics

Conventional weapon

Conventional weapon

The terms conventional weapons or conventional arms generally refer to weapons whose ability to damage comes from kinetic, incendiary, or explosive energy and exclude weapons of mass destruction. Conventional weapons include small arms, defensive shields and light weapons, sea and land mines, as well as bombs, shells, rockets, missiles and cluster munitions. These weapons use explosive material based on chemical energy, as opposed to nuclear energy in nuclear weapons.

Nuclear weapon

Nuclear weapon

A nuclear weapon is an explosive device that derives its destructive force from nuclear reactions, either fission or a combination of fission and fusion reactions, producing a nuclear explosion. Both bomb types release large quantities of energy from relatively small amounts of matter.

Chemical weapon

Chemical weapon

A chemical weapon (CW) is a specialized munition that uses chemicals formulated to inflict death or harm on humans. According to the Organisation for the Prohibition of Chemical Weapons (OPCW), this can be any chemical compound intended as a weapon "or its precursor that can cause death, injury, temporary incapacitation or sensory irritation through its chemical action. Munitions or other delivery devices designed to deliver chemical weapons, whether filled or unfilled, are also considered weapons themselves."

Organism

Organism

In biology, an organism is any living system that functions as an individual entity. All organisms are composed of cells. The idea of organism is based on the concept of minimal functional unit of life. Three traits have been proposed to play the main role in qualification as an organism:noncompartmentability – structure that cannot be divided without its functionality loss, individuality – the entity has simultaneous holding of genetic uniqueness, genetic homogeneity and autonomy, distinctness – genetic information has to maintain open-system.

Biological warfare

Biological warfare

Biological warfare, also known as germ warfare, is the use of biological toxins or infectious agents such as bacteria, viruses, insects, and fungi with the intent to kill, harm or incapacitate humans, animals or plants as an act of war. Biological weapons are living organisms or replicating entities. Entomological (insect) warfare is a subtype of biological warfare.

Botulinum toxin

Botulinum toxin

Botulinum toxin, or botulinum neurotoxin (BoNT), is a neurotoxic protein produced by the bacterium Clostridium botulinum and related species. It prevents the release of the neurotransmitter acetylcholine from axon endings at the neuromuscular junction, thus causing flaccid paralysis. The toxin causes the disease botulism. The toxin is also used commercially for medical and cosmetic purposes.

Ricin

Ricin

Ricin ( RY-sin) is a lectin (a carbohydrate-binding protein) and a highly potent toxin produced in the seeds of the castor oil plant, Ricinus communis. The median lethal dose (LD50) of ricin for mice is around 22 micrograms per kilogram of body weight via intraperitoneal injection. Oral exposure to ricin is far less toxic. An estimated lethal oral dose in humans is approximately 1 milligram per kilogram of body weight.

Saxitoxin

Saxitoxin

Saxitoxin (STX) is a potent neurotoxin and the best-known paralytic shellfish toxin (PST). Ingestion of saxitoxin by humans, usually by consumption of shellfish contaminated by toxic algal blooms, is responsible for the illness known as paralytic shellfish poisoning (PSP).

Chemical Weapons Convention

Chemical Weapons Convention

The Chemical Weapons Convention (CWC), officially the Convention on the Prohibition of the Development, Production, Stockpiling and Use of Chemical Weapons and on their Destruction, is an arms control treaty administered by the Organisation for the Prohibition of Chemical Weapons (OPCW), an intergovernmental organization based in The Hague, The Netherlands. The treaty entered into force on 29 April 1997, and prohibits the large-scale use, development, production, stockpiling and transfer of chemical weapons and their precursors, except for very limited purposes. The main obligation of member states under the convention is to effect this prohibition, as well as the destruction of all current chemical weapons. All destruction activities must take place under OPCW verification.

List of Schedule 1 substances (CWC)

List of Schedule 1 substances (CWC)

Schedule 1 substances, in the sense of the Chemical Weapons Convention, are chemicals which can either be used as chemical weapons themselves or used in the manufacture of chemical weapons and which have no, or very limited, uses outside of chemical warfare.

Lewisite

Lewisite

Lewisite (L) (A-243) is an organoarsenic compound. It was once manufactured in the U.S., Japan, Germany and the Soviet Union for use as a chemical weapon, acting as a vesicant and lung irritant. Although the substance is colorless and odorless in its pure form, impure samples of lewisite are a yellow, brown, violet-black, green, or amber oily liquid with a distinctive odor that has been described as similar to geraniums.

Mustard gas

Mustard gas

Mustard gas or sulfur mustard is any of several chemical compounds that contain the chemical structure SCH2CH2Cl. In the wider sense, compounds with the substituent SCH2CH2X and NCH2CH2X are known as sulfur mustards and nitrogen mustards (X = Cl, Br), respectively. Such compounds are potent alkylating agents, which can interfere with several biological processes. Also known as mustard agents, this family of compounds are infamous cytotoxic and blister agents. The name mustard gas is technically incorrect: the substances, when dispersed, are often not gases but a fine mist of liquid droplets. Mustard gases form blisters on exposed skin and in the lungs, often resulting in prolonged illness ending in death. The typical mustard gas is the organosulfur compound called bis(2-chloroethyl) sulfide.

John Singer Sargent's iconic World War I painting: Gassed, showing blind casualties on a battlefield after a mustard gas attack

Simple chemical weapons were used sporadically throughout antiquity and into the Industrial Age.^[5] It was not until the 19th century that the modern conception of chemical warfare emerged, as various scientists and nations proposed the use of asphyxiating or poisonous gasses.

Multiple international treaties were passed banning chemical weapons based upon the alarm of nations and scientists. This however did not prevent the extensive use of chemical weapons in World War I. The development of chlorine gas, among others, was used by both sides to try to break the stalemate of trench warfare. Though largely ineffective over the long run, it decidedly changed the nature of the war. In many cases the gasses used did not kill, but instead horribly maimed, injured, or disfigured casualties. Some 1.3 million gas casualties were recorded, which may have included up to 260,000 civilian casualties.^[6][7][8]

The interwar years saw the occasional use of chemical weapons, mainly to put down rebellions.^[9] In Nazi Germany, much research went into developing new chemical weapons, such as potent nerve agents.^[10] However, chemical weapons saw little battlefield use in World War II. Both sides were prepared to use such weapons, but the Allied Powers never did, and the Axis used them only very sparingly. The reason for the lack of use by the Nazis, despite the considerable efforts that had gone into developing new varieties, might have been a lack of technical ability or fears that the Allies would retaliate with their own chemical weapons. Those fears were not unfounded: the Allies made comprehensive plans for defensive and retaliatory use of chemical weapons, and stockpiled large quantities.^[11][12] Japanese forces, as part of the Axis, used them more widely, though only against their Asian enemies, as they also feared that using it on Western powers would result in retaliation. Chemical weapons were frequently used against the Kuomintang and Chinese communist troops, the People's Liberation Army.^[13] However, the Nazis did extensively use poison gas against civilians, mostly the genocide of European Jews, in The Holocaust. Vast quantities of Zyklon B gas and carbon monoxide were used in the gas chambers of Nazi extermination camps, resulting in the overwhelming majority of some three million deaths. This remains the deadliest use of poison gas in history.^{[14][15][16][17]}

Victims of Ghouta chemical attacks perpetrated by the forces of Syrian dictator Bashar al-Assad

Fritz Haber is considered the "father of chemical warfare" for his years of pioneering work developing and weaponizing chlorine and other poisonous gases during World War I.

The post-war era has seen limited, though devastating, use of chemical weapons. During the Vietnam War, between 1962 and 1971, the United States military sprayed nearly 20,000,000 U.S. gallons (76,000 m³) of various chemicals – the "rainbow herbicides" and defoliants – in Vietnam, eastern Laos, and parts of Cambodia as part of Operation Ranch Hand, reaching its peak from 1967 to 1969.^[18] Some 100,000 Iranian troops were casualties of Iraqi chemical weapons during the Iran–Iraq War.^[19][20][21] Iraq used mustard gas and nerve agents against its own civilians in the 1988 Halabja chemical attack.^[22] The Cuban intervention in Angola saw limited use of organophosphates.^[23] The Syrian government has used sarin, chlorine, and mustard gas in the Syrian civil war – mostly against civilians.^[24][25] Terrorist groups have also used chemical weapons, notably in the Tokyo subway sarin attack and the Matsumoto incident.^[26][27] See also chemical terrorism.

Discover more about History related topics

History of chemical warfare

History of chemical warfare

Chemical weapons have been a part of warfare in most societies, although their use has been particularly controversial since the 20th century.

John Singer Sargent

John Singer Sargent

John Singer Sargent was an American expatriate artist, considered the "leading portrait painter of his generation" for his evocations of Edwardian-era luxury. He created roughly 900 oil paintings and more than 2,000 watercolors, as well as countless sketches and charcoal drawings. His oeuvre documents worldwide travel, from Venice to the Tyrol, Corfu, Spain, the Middle East, Montana, Maine, and Florida.

Gassed (painting)

Gassed (painting)

Gassed is a very large oil painting completed in March 1919 by John Singer Sargent. It depicts the aftermath of a mustard gas attack during the First World War, with a line of wounded soldiers walking towards a dressing station. Sargent was commissioned by the British War Memorials Committee to document the war and visited the Western Front in July 1918 spending time with the Guards Division near Arras, and then with the American Expeditionary Forces near Ypres. The painting was finished in March 1919 and voted picture of the year by the Royal Academy of Arts in 1919. It is now held by the Imperial War Museum. It visited the US in 1999 for a series of retrospective exhibitions, and then from 2016 to 2018 for exhibitions commemorating the centenary of the First World War.

Industrial Age

Industrial Age

The Industrial Age is a period of history that encompasses the changes in economic and social organization that began around 1760 in Great Britain and later in other countries, characterized chiefly by the replacement of hand tools with power-driven machines such as the power loom and the steam engine, and by the concentration of industry in large establishments.

Chemical weapons in World War I

Chemical weapons in World War I

The use of toxic chemicals as weapons dates back thousands of years, but the first large scale use of chemical weapons was during World War I. They were primarily used to demoralize, injure, and kill entrenched defenders, against whom the indiscriminate and generally very slow-moving or static nature of gas clouds would be most effective. The types of weapons employed ranged from disabling chemicals, such as tear gas, to lethal agents like phosgene, chlorine, and mustard gas. This chemical warfare was a major component of the first global war and first total war of the 20th century. The killing capacity of gas was limited, with about 90,000 fatalities from a total of 1.3 million casualties caused by gas attacks. Gas was unlike most other weapons of the period because it was possible to develop countermeasures, such as gas masks. In the later stages of the war, as the use of gas increased, its overall effectiveness diminished. The widespread use of these agents of chemical warfare, and wartime advances in the composition of high explosives, gave rise to an occasionally expressed view of World War I as "the chemist's war" and also the era where weapons of mass destruction were created.

Chlorine

Chlorine

Chlorine is a chemical element with the symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine is a yellow-green gas at room temperature. It is an extremely reactive element and a strong oxidising agent: among the elements, it has the highest electron affinity and the third-highest electronegativity on the revised Pauling scale, behind only oxygen and fluorine.

Nazi Germany

Nazi Germany

Nazi Germany was the German state between 1933 and 1945, when Adolf Hitler and the Nazi Party controlled the country, transforming it into a dictatorship. Under Hitler's rule, Germany quickly became a totalitarian state where nearly all aspects of life were controlled by the government. The Third Reich, meaning "Third Realm" or "Third Empire", alluded to the Nazi claim that Nazi Germany was the successor to the earlier Holy Roman Empire (800–1806) and German Empire (1871–1918). The Third Reich, which Hitler and the Nazis referred to as the Thousand-Year Reich, ended in May 1945 after 12 years when the Allies defeated Germany, ending World War II in Europe.

Nerve agent

Nerve agent

Nerve agents, sometimes also called nerve gases, are a class of organic chemicals that disrupt the mechanisms by which nerves transfer messages to organs. The disruption is caused by the blocking of acetylcholinesterase (AChE), an enzyme that catalyzes the breakdown of acetylcholine, a neurotransmitter. Nerve agents are acetylcholinesterase inhibitors used as poison.

Axis powers

Axis powers

The Axis powers, originally called the Rome–Berlin Axis, was a military coalition that initiated World War II and fought against the Allies. Its principal members were Nazi Germany, the Kingdom of Italy, and the Empire of Japan. The Axis were united in their opposition to the Allies, but otherwise lacked comparable coordination and ideological cohesion.

Kuomintang

Kuomintang

The Kuomintang (KMT), also referred to as the Guomindang (GMD), the Nationalist Party of China (NPC) or the Chinese Nationalist Party (CNP), is a major political party in the Republic of China, initially on the Chinese mainland and then in Taiwan since 1949. It was the sole party in China during the Republican Era from 1928 to 1949, when most of the Chinese mainland was under its control. The party retreated from the mainland to Taiwan on 7 December 1949, following its defeat in the Chinese Civil War. Chiang Kai-shek declared martial law and retained its authoritarian rule over Taiwan under the Dang Guo system until democratic reforms were enacted in the 1980s and full democratization in the 1990s. In Taiwanese politics today, the KMT is a centre-right to right-wing party, and is the largest party in the Pan-Blue Coalition. The KMT's primary rival in elections is the Democratic Progressive Party (DPP) and its allies in the Pan-Green Coalition. As of 2023, the KMT is currently the largest opposition party in the Legislative Yuan. The current chairman is Eric Chu.

People's Liberation Army

People's Liberation Army

The People's Liberation Army (PLA) is the principal military force of the People's Republic of China and the armed wing of the Chinese Communist Party (CCP). The PLA consists of five service branches: the Ground Force, Navy, Air Force, Rocket Force, and Strategic Support Force. It is under the leadership of the Central Military Commission (CMC) with its chairman as commander-in-chief.

Carbon monoxide

Carbon monoxide

Carbon monoxide is a poisonous, flammable gas that is colorless, odorless, tasteless, and slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simplest carbon oxide. In coordination complexes the carbon monoxide ligand is called carbonyl. It is a key ingredient in many processes in industrial chemistry.

A Swedish Army soldier wearing a chemical agent protective suit (C-vätskeskydd) and protection mask (skyddsmask 90)

Although crude chemical warfare has been employed in many parts of the world for thousands of years,^[28] "modern" chemical warfare began during World War I – see Chemical weapons in World War I.

Initially, only well-known commercially available chemicals and their variants were used. These included chlorine and phosgene gas. The methods used to disperse these agents during battle were relatively unrefined and inefficient. Even so, casualties could be heavy, due to the mainly static troop positions which were characteristic features of trench warfare.

Germany, the first side to employ chemical warfare on the battlefield,^[29] simply opened canisters of chlorine upwind of the opposing side and let the prevailing winds do the dissemination. Soon after, the French modified artillery munitions to contain phosgene – a much more effective method that became the principal means of delivery.^[30]

Since the development of modern chemical warfare in World War I, nations have pursued research and development on chemical weapons that falls into four major categories: new and more deadly agents; more efficient methods of delivering agents to the target (dissemination); more reliable means of defense against chemical weapons; and more sensitive and accurate means of detecting chemical agents.

Chemical warfare agents

The chemical used in warfare is called a chemical warfare agent (CWA). About 70 different chemicals have been used or stockpiled as chemical warfare agents during the 20th and 21st centuries. These agents may be in liquid, gas or solid form. Liquid agents that evaporate quickly are said to be volatile or have a high vapor pressure. Many chemical agents are volatile organic compounds so they can be dispersed over a large region quickly.^[31]

The earliest target of chemical warfare agent research was not toxicity, but development of agents that can affect a target through the skin and clothing, rendering protective gas masks useless. In July 1917, the Germans employed sulfur mustard. Mustard agents easily penetrate leather and fabric to inflict painful burns on the skin.

Chemical warfare agents are divided into lethal and incapacitating categories. A substance is classified as incapacitating if less than 1/100 of the lethal dose causes incapacitation, e.g., through nausea or visual problems. The distinction between lethal and incapacitating substances is not fixed, but relies on a statistical average called the LD₅₀.

Persistency

Chemical warfare agents can be classified according to their persistency, a measure of the length of time that a chemical agent remains effective after dissemination. Chemical agents are classified as persistent or nonpersistent.

Agents classified as nonpersistent lose effectiveness after only a few minutes or hours or even only a few seconds. Purely gaseous agents such as chlorine are nonpersistent, as are highly volatile agents such as sarin. Tactically, nonpersistent agents are very useful against targets that are to be taken over and controlled very quickly.

Apart from the agent used, the delivery mode is very important. To achieve a nonpersistent deployment, the agent is dispersed into very small droplets comparable with the mist produced by an aerosol can. In this form not only the gaseous part of the agent (around 50%) but also the fine aerosol can be inhaled or absorbed through pores in the skin.

Modern doctrine requires very high concentrations almost instantly in order to be effective (one breath should contain a lethal dose of the agent). To achieve this, the primary weapons used would be rocket artillery or bombs and large ballistic missiles with cluster warheads. The contamination in the target area is only low or not existent and after four hours sarin or similar agents are not detectable anymore.

By contrast, persistent agents tend to remain in the environment for as long as several weeks, complicating decontamination. Defense against persistent agents requires shielding for extended periods of time. Nonvolatile liquid agents, such as blister agents and the oily VX nerve agent, do not easily evaporate into a gas, and therefore present primarily a contact hazard.

The droplet size used for persistent delivery goes up to 1 mm increasing the falling speed and therefore about 80% of the deployed agent reaches the ground, resulting in heavy contamination. Deployment of persistent agents is intended to constrain enemy operations by denying access to contaminated areas.

Possible targets include enemy flank positions (averting possible counterattacks), artillery regiments, command posts or supply lines. Because it is not necessary to deliver large quantities of the agent in a short period of time, a wide variety of weapons systems can be used.

A special form of persistent agents are thickened agents. These comprise a common agent mixed with thickeners to provide gelatinous, sticky agents. Primary targets for this kind of use include airfields, due to the increased persistency and difficulty of decontaminating affected areas.

Classes

Chemical weapons are agents that come in four categories: choking, blister, blood and nerve.^[32] The agents are organized into several categories according to the manner in which they affect the human body. The names and number of categories varies slightly from source to source, but in general, types of chemical warfare agents are as follows:

There are other chemicals used militarily that are not scheduled by the CWC, and thus are not controlled under the CWC treaties. These include:

• Defoliants and herbicides that destroy vegetation, but are not immediately toxic or poisonous to human beings. Their use is classified as herbicidal warfare. Some batches of Agent Orange, for instance, used by the British during the Malayan Emergency and the United States during the Vietnam War, contained dioxins as manufacturing impurities. Dioxins, rather than Agent Orange itself, have long-term cancer effects and for causing genetic damage leading to serious birth defects.
• Incendiary or explosive chemicals (such as napalm, extensively used by the United States during the Korean War and the Vietnam War, or dynamite) because their destructive effects are primarily due to fire or explosive force, and not direct chemical action. Their use is classified as conventional warfare.
• Viruses, bacteria, or other organisms. Their use is classified as biological warfare. Toxins produced by living organisms are considered chemical weapons, although the boundary is blurry. Toxins are covered by the Biological Weapons Convention.

Designations

Most chemical weapons are assigned a one- to three-letter "NATO weapon designation" in addition to, or in place of, a common name. Binary munitions, in which precursors for chemical warfare agents are automatically mixed in shell to produce the agent just prior to its use, are indicated by a "-2" following the agent's designation (for example, GB-2 and VX-2).

Some examples are given below:

Delivery

The most important factor in the effectiveness of chemical weapons is the efficiency of its delivery, or dissemination, to a target. The most common techniques include munitions (such as bombs, projectiles, warheads) that allow dissemination at a distance and spray tanks which disseminate from low-flying aircraft. Developments in the techniques of filling and storage of munitions have also been important.

Although there have been many advances in chemical weapon delivery since World War I, it is still difficult to achieve effective dispersion. The dissemination is highly dependent on atmospheric conditions because many chemical agents act in gaseous form. Thus, weather observations and forecasting are essential to optimize weapon delivery and reduce the risk of injuring friendly forces.

Dispersion

Dispersion of chlorine in World War I

Dispersion is placing the chemical agent upon or adjacent to a target immediately before dissemination, so that the material is most efficiently used. Dispersion is the simplest technique of delivering an agent to its target. The most common techniques are munitions, bombs, projectiles, spray tanks and warheads.

World War I saw the earliest implementation of this technique. The actual first chemical ammunition was the French 26 mm cartouche suffocante rifle grenade, fired from a flare carbine. It contained 35g of the tear-producer ethyl bromoacetate, and was used in autumn 1914 – with little effect on the Germans.

The German military contrarily tried to increase the effect of 10.5 cm shrapnel shells by adding an irritant – dianisidine chlorosulfonate. Its use went unnoticed by the British when it was used against them at Neuve Chapelle in October 1914. Hans Tappen, a chemist in the Heavy Artillery Department of the War Ministry, suggested to his brother, the Chief of the Operations Branch at German General Headquarters, the use of the tear-gases benzyl bromide or xylyl bromide.

Shells were tested successfully at the Wahn artillery range near Cologne on January 9, 1915, and an order was placed for 15 cm howitzer shells, designated 'T-shells' after Tappen. A shortage of shells limited the first use against the Russians at the Battle of Bolimów on January 31, 1915; the liquid failed to vaporize in the cold weather, and again the experiment went unnoticed by the Allies.

The first effective use were when the German forces at the Second Battle of Ypres simply opened cylinders of chlorine and allowed the wind to carry the gas across enemy lines. While simple, this technique had numerous disadvantages. Moving large numbers of heavy gas cylinders to the front-line positions from where the gas would be released was a lengthy and difficult logistical task.

Aerial photograph of a German gas attack on Russian forces circa 1916

Stockpiles of cylinders had to be stored at the front line, posing a great risk if hit by artillery shells. Gas delivery depended greatly on wind speed and direction. If the wind was fickle, as at the Battle of Loos, the gas could blow back, causing friendly casualties.

Gas clouds gave plenty of warning, allowing the enemy time to protect themselves, though many soldiers found the sight of a creeping gas cloud unnerving. This made the gas doubly effective, as, in addition to damaging the enemy physically, it also had a psychological effect on the intended victims.

Another disadvantage was that gas clouds had limited penetration, capable only of affecting the front-line trenches before dissipating. Although it produced limited results in World War I, this technique shows how simple chemical weapon dissemination can be.

Shortly after this "open canister" dissemination, French forces developed a technique for delivery of phosgene in a non-explosive artillery shell. This technique overcame many of the risks of dealing with gas in cylinders. First, gas shells were independent of the wind and increased the effective range of gas, making any target within reach of guns vulnerable. Second, gas shells could be delivered without warning, especially the clear, nearly odorless phosgene—there are numerous accounts of gas shells, landing with a "plop" rather than exploding, being initially dismissed as dud high explosive or shrapnel shells, giving the gas time to work before the soldiers were alerted and took precautions.

The major drawback of artillery delivery was the difficulty of achieving a killing concentration. Each shell had a small gas payload and an area would have to be subjected to saturation bombardment to produce a cloud to match cylinder delivery. A British solution to the problem was the Livens Projector. This was effectively a large-bore mortar, dug into the ground that used the gas cylinders themselves as projectiles – firing a 14 kg cylinder up to 1500 m. This combined the gas volume of cylinders with the range of artillery.

Over the years, there were some refinements in this technique. In the 1950s and early 1960s, chemical artillery rockets and cluster bombs contained a multitude of submunitions, so that a large number of small clouds of the chemical agent would form directly on the target.

Thermal dissemination

An American-made MC-1 gas bomb

Thermal dissemination is the use of explosives or pyrotechnics to deliver chemical agents. This technique, developed in the 1920s, was a major improvement over earlier dispersal techniques, in that it allowed significant quantities of an agent to be disseminated over a considerable distance. Thermal dissemination remains the principal method of disseminating chemical agents today.

Most thermal dissemination devices consist of a bomb or projectile shell that contains a chemical agent and a central "burster" charge; when the burster detonates, the agent is expelled laterally.

Thermal dissemination devices, though common, are not particularly efficient. First, a percentage of the agent is lost by incineration in the initial blast and by being forced onto the ground. Second, the sizes of the particles vary greatly because explosive dissemination produces a mixture of liquid droplets of variable and difficult to control sizes.

The efficacy of thermal detonation is greatly limited by the flammability of some agents. For flammable aerosols, the cloud is sometimes totally or partially ignited by the disseminating explosion in a phenomenon called flashing. Explosively disseminated VX will ignite roughly one third of the time. Despite a great deal of study, flashing is still not fully understood, and a solution to the problem would be a major technological advance.

Despite the limitations of central bursters, most nations use this method in the early stages of chemical weapon development, in part because standard munitions can be adapted to carry the agents.

Soviet chemical weapons canisters from a stockpile in Albania

Aerodynamic dissemination

Aerodynamic dissemination is the non-explosive delivery of a chemical agent from an aircraft, allowing aerodynamic stress to disseminate the agent. This technique is the most recent major development in chemical agent dissemination, originating in the mid-1960s.

This technique eliminates many of the limitations of thermal dissemination by eliminating the flashing effect and theoretically allowing precise control of particle size. In actuality, the altitude of dissemination, wind direction and velocity, and the direction and velocity of the aircraft greatly influence particle size. There are other drawbacks as well; ideal deployment requires precise knowledge of aerodynamics and fluid dynamics, and because the agent must usually be dispersed within the boundary layer (less than 200–300 ft or 61–91 m above the ground), it puts pilots at risk.

Significant research is still being applied toward this technique. For example, by modifying the properties of the liquid, its breakup when subjected to aerodynamic stress can be controlled and an idealized particle distribution achieved, even at supersonic speed. Additionally, advances in fluid dynamics, computer modeling, and weather forecasting allow an ideal direction, speed, and altitude to be calculated, such that warfare agent of a predetermined particle size can predictably and reliably hit a target.

Protection against chemical warfare

Israel Defense Forces "Yanshuf" battalion soldiers at chemical warfare defense exercise

Ideal protection begins with nonproliferation treaties such as the CWC, and detecting, very early, the signatures of someone building a chemical weapons capability. These include a wide range of intelligence disciplines, such as economic analysis of exports of dual-use chemicals and equipment, human intelligence (HUMINT) such as diplomatic, refugee, and agent reports; photography from satellites, aircraft and drones (IMINT); examination of captured equipment (TECHINT); communications intercepts (COMINT); and detection of chemical manufacturing and chemical agents themselves (MASINT).

If all the preventive measures fail and there is a clear and present danger, then there is a need for detection of chemical attacks,^[33] collective protection,^[34][35][36] and decontamination. Since industrial accidents can cause dangerous chemical releases (e.g., the Bhopal disaster), these activities are things that civilian, as well as military, organizations must be prepared to carry out. In civilian situations in developed countries, these are duties of HAZMAT organizations, which most commonly are part of fire departments.

Detection has been referred to above, as a technical MASINT discipline; specific military procedures, which are usually the model for civilian procedures, depend on the equipment, expertise, and personnel available. When chemical agents are detected, an alarm needs to sound, with specific warnings over emergency broadcasts and the like. There may be a warning to expect an attack.

If, for example, the captain of a US Navy ship believes there is a serious threat of chemical, biological, or radiological attack, the crew may be ordered to set Circle William, which means closing all openings to outside air, running breathing air through filters, and possibly starting a system that continually washes down the exterior surfaces. Civilian authorities dealing with an attack or a toxic chemical accident will invoke the Incident Command System, or local equivalent, to coordinate defensive measures.^[36]

Individual protection starts with a gas mask and, depending on the nature of the threat, through various levels of protective clothing up to a complete chemical-resistant suit with a self-contained air supply. The US military defines various levels of MOPP (mission-oriented protective posture) from mask to full chemical resistant suits; Hazmat suits are the civilian equivalent, but go farther to include a fully independent air supply, rather than the filters of a gas mask.

Collective protection allows continued functioning of groups of people in buildings or shelters, the latter which may be fixed, mobile, or improvised. With ordinary buildings, this may be as basic as plastic sheeting and tape, although if the protection needs to be continued for any appreciable length of time, there will need to be an air supply, typically an enhanced gas mask.^[35][36]

Members of the Ukrainian Army's 19th Nuclear, Biological and Chemical Battalion practice decontamination drill, at Camp Arifjan, Kuwait

Decontamination

Decontamination varies with the particular chemical agent used. Some nonpersistent agents, including most pulmonary agents (chlorine, phosgene, and so on), blood gases, and nonpersistent nerve gases (e.g., GB), will dissipate from open areas, although powerful exhaust fans may be needed to clear out buildings where they have accumulated.

In some cases, it might be necessary to neutralize them chemically, as with ammonia as a neutralizer for hydrogen cyanide or chlorine. Riot control agents such as CS will dissipate in an open area, but things contaminated with CS powder need to be aired out, washed by people wearing protective gear, or safely discarded.

Mass decontamination is a less common requirement for people than equipment, since people may be immediately affected and treatment is the action required. It is a requirement when people have been contaminated with persistent agents. Treatment and decontamination may need to be simultaneous, with the medical personnel protecting themselves so they can function.^[37]

There may need to be immediate intervention to prevent death, such as injection of atropine for nerve agents. Decontamination is especially important for people contaminated with persistent agents; many of the fatalities after the explosion of a WWII US ammunition ship carrying sulfur mustard, in the harbor of Bari, Italy, after a German bombing on December 2, 1943, came when rescue workers, not knowing of the contamination, bundled cold, wet seamen in tight-fitting blankets.

For decontaminating equipment and buildings exposed to persistent agents, such as blister agents, VX or other agents made persistent by mixing with a thickener, special equipment and materials might be needed. Some type of neutralizing agent will be needed; e.g. in the form of a spraying device with neutralizing agents such as Chlorine, Fichlor, strong alkaline solutions or enzymes. In other cases, a specific chemical decontaminant will be required.^[36]

Discover more about Technology related topics

Chemical weapon

Chemical weapon

A chemical weapon (CW) is a specialized munition that uses chemicals formulated to inflict death or harm on humans. According to the Organisation for the Prohibition of Chemical Weapons (OPCW), this can be any chemical compound intended as a weapon "or its precursor that can cause death, injury, temporary incapacitation or sensory irritation through its chemical action. Munitions or other delivery devices designed to deliver chemical weapons, whether filled or unfilled, are also considered weapons themselves."

Chlorine

Chlorine

Chlorine is a chemical element with the symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine is a yellow-green gas at room temperature. It is an extremely reactive element and a strong oxidising agent: among the elements, it has the highest electron affinity and the third-highest electronegativity on the revised Pauling scale, behind only oxygen and fluorine.

Chloropicrin

Chloropicrin

Chloropicrin, also known as PS and nitrochloroform, is a chemical compound currently used as a broad-spectrum antimicrobial, fungicide, herbicide, insecticide, and nematicide. It was used as a poison gas in World War I. Its chemical structural formula is Cl3CNO2.

Phosgene

Phosgene

Phosgene is the organic chemical compound with the formula COCl2. It is a toxic, colorless gas; in low concentrations, its musty odor resembles that of freshly cut hay or grass. It can be thought of as formaldehyde with the hydrogen atoms replaced by chlorine atoms. Phosgene is a valued and important industrial building block, especially for the production of precursors of polyurethanes and polycarbonate plastics.

Lewisite

Lewisite

Lewisite (L) (A-243) is an organoarsenic compound. It was once manufactured in the U.S., Japan, Germany and the Soviet Union for use as a chemical weapon, acting as a vesicant and lung irritant. Although the substance is colorless and odorless in its pure form, impure samples of lewisite are a yellow, brown, violet-black, green, or amber oily liquid with a distinctive odor that has been described as similar to geraniums.

Swedish Army

Swedish Army

The Swedish Army is the land force of the Swedish Armed Forces.

Gas mask

Gas mask

A gas mask is a mask used to protect the wearer from inhaling airborne pollutants and toxic gases. The mask forms a sealed cover over the nose and mouth, but may also cover the eyes and other vulnerable soft tissues of the face. Most gas masks are also respirators, though the word gas mask is often used to refer to military equipment, the scope used in this article. The gas mask only protects the user from digesting, inhaling, and contact through the eyes. Most combined gas mask filters will last around 8 hours in a biological or chemical situation. Filters against specific chemical agents can last up to 20 hours.

Chemical weapons in World War I

Chemical weapons in World War I

The use of toxic chemicals as weapons dates back thousands of years, but the first large scale use of chemical weapons was during World War I. They were primarily used to demoralize, injure, and kill entrenched defenders, against whom the indiscriminate and generally very slow-moving or static nature of gas clouds would be most effective. The types of weapons employed ranged from disabling chemicals, such as tear gas, to lethal agents like phosgene, chlorine, and mustard gas. This chemical warfare was a major component of the first global war and first total war of the 20th century. The killing capacity of gas was limited, with about 90,000 fatalities from a total of 1.3 million casualties caused by gas attacks. Gas was unlike most other weapons of the period because it was possible to develop countermeasures, such as gas masks. In the later stages of the war, as the use of gas increased, its overall effectiveness diminished. The widespread use of these agents of chemical warfare, and wartime advances in the composition of high explosives, gave rise to an occasionally expressed view of World War I as "the chemist's war" and also the era where weapons of mass destruction were created.

Prevailing winds

Prevailing winds

In meteorology, prevailing wind in a region of the Earth's surface is a surface wind that blows predominantly from a particular direction. The dominant winds are the trends in direction of wind with the highest speed over a particular point on the Earth's surface at any given time. A region's prevailing and dominant winds are the result of global patterns of movement in the Earth's atmosphere. In general, winds are predominantly easterly at low latitudes globally. In the mid-latitudes, westerly winds are dominant, and their strength is largely determined by the polar cyclone. In areas where winds tend to be light, the sea breeze/land breeze cycle is the most important cause of the prevailing wind; in areas which have variable terrain, mountain and valley breezes dominate the wind pattern. Highly elevated surfaces can induce a thermal low, which then augments the environmental wind flow.

Artillery

Artillery

Artillery is a class of heavy military ranged weapons that launch munitions far beyond the range and power of infantry firearms. Early artillery development focused on the ability to breach defensive walls and fortifications during sieges, and led to heavy, fairly immobile siege engines. As technology improved, lighter, more mobile field artillery cannons developed for battlefield use. This development continues today; modern self-propelled artillery vehicles are highly mobile weapons of great versatility generally providing the largest share of an army's total firepower.

Research and development

Research and development

Research and development, known in Europe as research and technological development (RTD), is the set of innovative activities undertaken by corporations or governments in developing new services or products, and improving existing ones. Research and development constitutes the first stage of development of a potential new service or the production process.

List of chemical warfare agents

List of chemical warfare agents

A chemical weapon agent (CWA), or chemical warfare agent, is a chemical substance whose toxic properties are meant to kill, injure or incapacitate human beings. About 70 different chemicals have been used or stockpiled as chemical weapon agents during the 20th century. These agents may be in liquid, gas or solid form.

There are many instances of the use of chemical weapons in battles documented in Greek and Roman historical texts; the earliest example was the deliberate poisoning of Kirrha's water supply with hellebore in the First Sacred War, Greece, about 590 BC.^[38]

One of the earliest reactions to the use of chemical agents was from Rome. Struggling to defend themselves from the Roman legions, Germanic tribes poisoned the wells of their enemies, with Roman jurists having been recorded as declaring "armis bella non venenis geri", meaning "war is fought with weapons, not with poisons." Yet the Romans themselves resorted to poisoning wells of besieged cities in Anatolia in the 2nd century BCE.^[39]

Before 1915 the use of poisonous chemicals in battle was typically the result of local initiative, and not the result of an active government chemical weapons program. There are many reports of the isolated use of chemical agents in individual battles or sieges, but there was no true tradition of their use outside of incendiaries and smoke. Despite this tendency, there have been several attempts to initiate large-scale implementation of poison gas in several wars, but with the notable exception of World War I, the responsible authorities generally rejected the proposals for ethical reasons or fears of retaliation.

For example, in 1854 Lyon Playfair (later 1st Baron Playfair, GCB, PC, FRS (1818–1898), a British chemist, proposed using a cacodyl cyanide-filled artillery shell against enemy ships during the Crimean War. The British Ordnance Department rejected the proposal as "as bad a mode of warfare as poisoning the wells of the enemy."

Efforts to eradicate chemical weapons

• August 27, 1874: The Brussels Declaration Concerning the Laws and Customs of War is signed, specifically forbidding the "employment of poison or poisoned weapons", although the treaty was not adopted by any nation whatsoever and it never went into effect.
• September 4, 1900: The First Hague Convention, which includes a declaration banning the "use of projectiles the object of which is the diffusion of asphyxiating or deleterious gases," enters into force.
• January 26, 1910: The Second Hague Convention enters into force, prohibiting the use of "poison or poisoned weapons" in warfare.
• February 6, 1922: After World War I, the Washington Arms Conference Treaty prohibited the use of asphyxiating, poisonous or other gases. It was signed by the United States, Britain, Japan, France, and Italy, but France objected to other provisions in the treaty and it never went into effect.
• February 8, 1928: The Geneva Protocol enters into force, prohibiting the use of "asphyxiating, poisonous or other gases, and of all analogous liquids, materials or devices" and "bacteriological methods of warfare".

Chemical weapon proliferation

Despite numerous efforts to reduce or eliminate them, some nations continue to research and/or stockpile chemical warfare agents. To the right is a summary of the nations that have either declared weapon stockpiles or are suspected of secretly stockpiling or possessing CW research programs. Notable examples include United States and Russia.

In 1997, future US Vice President Dick Cheney opposed the signing ratification of a treaty banning the use of chemical weapons, a recently unearthed letter shows. In a letter dated April 8, 1997, then Halliburton-CEO Cheney told Sen. Jesse Helms, the chairman of the Senate Foreign Relations Committee, that it would be a mistake for America to join the convention. "Those nations most likely to comply with the Chemical Weapons Convention are not likely to ever constitute a military threat to the United States. The governments we should be concerned about are likely to cheat on the CWC, even if they do participate," reads the letter,^[43] published by the Federation of American Scientists.

The CWC was ratified by the Senate that same month. Since then, Albania, Libya, Russia, the United States, and India have declared over 71,000 metric tons of chemical weapon stockpiles, and destroyed about a third of them. Under the terms of the agreement, the United States and Russia agreed to eliminate the rest of their supplies of chemical weapons by 2012. Not having met its goal, the U.S. government estimates remaining stocks will be destroyed by 2017.

Discover more about Sociopolitical climate related topics

Hellebore

Hellebore

Commonly known as hellebores, the Eurasian genus Helleborus consists of approximately 20 species of herbaceous or evergreen perennial flowering plants in the family Ranunculaceae, within which it gave its name to the tribe of Helleboreae. Despite names such as "winter rose", "Christmas rose" and "Lenten rose", hellebores are not closely related to the rose family (Rosaceae). Many hellebore species are poisonous.

First Sacred War

First Sacred War

The First Sacred War, or Cirraean War, was fought between the Amphictyonic League of Delphi and the city of Kirrha. At the beginning of the 6th century BC the Pylaeo-Delphic Amphictyony, controlled by the Thessalians, attempted to take hold of the Sacred Land of Apollo which resulted in this war. The conflict arose due to Kirrha's frequent robbery and mistreatment of pilgrims going to Delphi and their encroachments upon Delphic land. The war, which culminated with the defeat and destruction of Kirrha, is notable for the use of chemical warfare at the Siege of Kirrha, in the form of hellebore being used to poison the city's water supply. The war's end was marked by the organization of the first Pythian Games.

Germanic peoples

Germanic peoples

The Germanic peoples were historical groups of people that once occupied Central Europe and Scandinavia during antiquity and into the early Middle Ages. Since the 19th century, they have traditionally been defined by the use of ancient and early medieval Germanic languages and are thus equated at least approximately with Germanic-speaking peoples, although different academic disciplines have their own definitions of what makes someone or something "Germanic". The Romans named the area belonging to North-Central Europe in which Germanic peoples lived Germania, stretching East to West between the Vistula and Rhine rivers and north to south from Southern Scandinavia to the upper Danube. In discussions of the Roman period, the Germanic peoples are sometimes referred to as Germani or ancient Germans, although many scholars consider the second term problematic since it suggests identity with present-day Germans. The very concept of "Germanic peoples" has become the subject of controversy among contemporary scholars. Some scholars call for its total abandonment as a modern construct since lumping "Germanic peoples" together implies a common group identity for which there is little evidence. Other scholars have defended the term's continued use and argue that a common Germanic language allows one to speak of "Germanic peoples", regardless of whether these ancient and medieval peoples saw themselves as having a common identity.

Incendiary device

Incendiary device

Incendiary weapons, incendiary devices, incendiary munitions, or incendiary bombs are weapons designed to start fires or destroy sensitive equipment using fire, that use materials such as napalm, thermite, magnesium powder, chlorine trifluoride, or white phosphorus. Though colloquially often known as bombs, they are not explosives but in fact are designed to slow the process of chemical reactions and use ignition rather than detonation to start or maintain the reaction. Napalm, for example, is petroleum especially thickened with certain chemicals into a 'gel' to slow, but not stop, combustion, releasing energy over a longer time than an explosive device. In the case of napalm, the gel adheres to surfaces and resists suppression.

Cacodyl cyanide

Cacodyl cyanide

Cacodyl cyanide is a highly poisonous organoarsenic compound discovered by Robert Bunsen in the 1840s. It is very volatile and flammable, as it shares the chemical properties of both arsenic and cyanide.

Artillery

Artillery

Artillery is a class of heavy military ranged weapons that launch munitions far beyond the range and power of infantry firearms. Early artillery development focused on the ability to breach defensive walls and fortifications during sieges, and led to heavy, fairly immobile siege engines. As technology improved, lighter, more mobile field artillery cannons developed for battlefield use. This development continues today; modern self-propelled artillery vehicles are highly mobile weapons of great versatility generally providing the largest share of an army's total firepower.

Crimean War

Crimean War

The Crimean War was fought from October 1853 to February 1856 between Russia and an ultimately victorious alliance of the Ottoman Empire, France, the United Kingdom and Sardinia-Piedmont.

Albania

Albania

Albania, officially the Republic of Albania, is a country in Southeastern Europe. It is situated in the Balkans, and is located on the Adriatic and Ionian Seas within the Mediterranean Sea and shares land borders with Montenegro to the northwest, Kosovo to the northeast, North Macedonia to the east, and Greece to the south. The country displays varied climatic, geological, hydrological, and morphological conditions, in an area of 28,748 km2 (11,100 sq mi). The landscape ranges from the snow-capped mountains in the Albanian Alps and the Korab, Skanderbeg, Pindus, and Ceraunian Mountains, to the hot and sunny coasts of the Adriatic and Ionian Seas along the Mediterranean. Tirana is its capital and largest city, followed by Durrës, Vlorë, and Shkodër.

China

China

China, officially the People's Republic of China (PRC), is a country in East Asia. It is the world's most populous country, with a population exceeding 1.4 billion, slightly ahead of India. China spans the equivalent of five time zones and borders fourteen countries by land, the most of any country in the world, tied with Russia. With an area of approximately 9.6 million square kilometres (3,700,000 sq mi), it is the world's third largest country by total land area. The country consists of 22 provinces, five autonomous regions, four municipalities, and two special administrative regions. The national capital is Beijing, and the most populous city and largest financial center is Shanghai.

Egypt

Egypt

Egypt, officially the Arab Republic of Egypt, is a transcontinental country spanning the northeast corner of Africa and southwest corner of Asia via a land bridge formed by the Sinai Peninsula. It is bordered by the Mediterranean Sea to the north, the Gaza Strip of Palestine and Israel to the northeast, the Red Sea to the east, Sudan to the south, and Libya to the west. The Gulf of Aqaba in the northeast separates Egypt from Jordan and Saudi Arabia. Cairo is the capital and largest city of Egypt, while Alexandria, the second-largest city, is an important industrial and tourist hub at the Mediterranean coast. At approximately 100 million inhabitants, Egypt is the 14th-most populated country in the world.

India

India

India, officially the Republic of India, is a country in South Asia. It is the seventh-largest country by area and the second-most populous country. Bounded by the Indian Ocean on the south, the Arabian Sea on the southwest, and the Bay of Bengal on the southeast, it shares land borders with Pakistan to the west; China, Nepal, and Bhutan to the north; and Bangladesh and Myanmar to the east. In the Indian Ocean, India is in the vicinity of Sri Lanka and the Maldives; its Andaman and Nicobar Islands share a maritime border with Thailand, Myanmar, and Indonesia.

Iran

Iran

Iran, officially the Islamic Republic of Iran and also called Persia, is a country located in Western Asia. It is bordered by Iraq and Turkey to the west, by Azerbaijan and Armenia to the northwest, by the Caspian Sea and Turkmenistan to the north, by Afghanistan and Pakistan to the east, and by the Gulf of Oman and the Persian Gulf to the south. It covers an area of 1.64 million square kilometres, making it the 17th-largest country. Iran has an estimated population of 86.8 million, making it the 17th-most populous country in the world, and the second-largest in the Middle East. Its largest cities, in descending order, are the capital Tehran, Mashhad, Isfahan, Karaj, Shiraz, and Tabriz.

India

In June 1997, India declared that it had a stockpile of 1044 tons of sulphur mustard in its possession. India's declaration of its stockpile came after its entry into the Chemical Weapons Convention, that created the Organisation for the Prohibition of Chemical Weapons, and on January 14, 1993, India became one of the original signatories to the Chemical Weapons Convention. By 2005, from among six nations that had declared their possession of chemical weapons, India was the only country to meet its deadline for chemical weapons destruction and for inspection of its facilities by the Organisation for the Prohibition of Chemical Weapons.^[44][45] By 2006, India had destroyed more than 75 percent of its chemical weapons and material stockpile and was granted an extension to complete a 100 percent destruction of its stocks by April 2009. On May 14, 2009, India informed the United Nations that it has completely destroyed its stockpile of chemical weapons.^[46]

Iraq

The Director-General of the Organisation for the Prohibition of Chemical Weapons, Ambassador Rogelio Pfirter, welcomed Iraq's decision to join the OPCW as a significant step to strengthening global and regional efforts to prevent the spread and use of chemical weapons. The OPCW announced "The government of Iraq has deposited its instrument of accession to the Chemical Weapons Convention with the Secretary General of the United Nations and within 30 days, on 12 February 2009, will become the 186th State Party to the Convention". Iraq has also declared stockpiles of chemical weapons, and because of their recent accession is the only State Party exempted from the destruction time-line.^[47]

Japan

During the Second Sino-Japanese War (1937–1945) Japan stored chemical weapons on the territory of mainland China. The weapon stock mostly containing sulfur mustard-lewisite mixture.^[48] The weapons are classified as abandoned chemical weapons under the Chemical Weapons Convention, and from September 2010 Japan has started their destruction in Nanjing using mobile destruction facilities in order to do so.^[49]

Russia

Russia signed into the Chemical Weapons Convention on January 13, 1993, and ratified it on November 5, 1995. Declaring an arsenal of 39,967 tons of chemical weapons in 1997, by far the largest arsenal, consisting of blister agents: Lewisite, Sulfur mustard, Lewisite-mustard mix, and nerve agents: Sarin, Soman, and VX. Russia met its treaty obligations by destroying 1 percent of its chemical agents by the 2002 deadline set out by the Chemical Weapons Convention, but requested an extension on the deadlines of 2004 and 2007 due to technical, financial, and environmental challenges of chemical disposal. Since, Russia has received help from other countries such as Canada which donated C$100,000, plus a further C$100,000 already donated, to the Russian Chemical Weapons Destruction Program. This money will be used to complete work at Shchuch'ye and support the construction of a chemical weapons destruction facility at Kizner (Russia), where the destruction of nearly 5,700 tons of nerve agent, stored in approximately 2 million artillery shells and munitions, will be undertaken. Canadian funds are also being used for the operation of a Green Cross Public Outreach Office, to keep the civilian population informed on the progress made in chemical weapons destruction activities.^[50]

As of July 2011, Russia has destroyed 48 percent (18,241 tons) of its stockpile at destruction facilities located in Gorny (Saratov Oblast) and Kambarka (Udmurt Republic) – where operations have finished – and Schuch'ye (Kurgan Oblast), Maradykovsky (Kirov Oblast), Leonidovka (Penza Oblast) whilst installations are under construction in Pochep (Bryansk Oblast) and Kizner (Udmurt Republic).^[51] As August 2013, 76 percent (30,500 tons) were destroyed,^[52] and Russia leaves the Cooperative Threat Reduction (CTR) Program, which partially funded chemical weapons destruction.^[53]

In September 2017, OPCW announced that Russia had destroyed its entire chemical weapons stockpile.^[54]

United States

On November 25, 1969, President Richard Nixon unilaterally renounced the offensive use of biological and toxic weapons, but the U.S. continued to maintain an offensive chemical weapons program.^[55]

From May 1964 to the early 1970s the U.S. participated in Operation CHASE, a United States Department of Defense program that aimed to dispose of chemical weapons by sinking ships laden with the weapons in the deep Atlantic. After the Marine Protection, Research, and Sanctuaries Act of 1972, Operation Chase was scrapped and safer disposal methods for chemical weapons were researched, with the U.S. destroying several thousand tons of sulfur mustard by incineration at the Rocky Mountain Arsenal, and nearly 4,200 tons of nerve agent by chemical neutralisation at Tooele Army Depot.^[56]

The U.S. began stockpile reductions in the 1980s with the removal of outdated munitions and destroying its entire stock of 3-Quinuclidinyl benzilate (BZ or Agent 15) at the beginning of 1988. In June 1990 the Johnston Atoll Chemical Agent Disposal System began destruction of chemical agents stored on the Johnston Atoll in the Pacific, seven years before the Chemical Weapons Treaty came into effect. In 1986 President Ronald Reagan made an agreement with the Chancellor, Helmut Kohl to remove the U.S. stockpile of chemical weapons from Germany. In 1990, as part of Operation Steel Box, two ships were loaded with over 100,000 shells containing Sarin and VX were taken from the U.S. Army weapons storage depots such as Miesau and then-classified FSTS (Forward Storage / Transportation Sites) and transported from Bremerhaven, Germany to Johnston Atoll in the Pacific, a 46-day nonstop journey.^[57]

In the 1980s, Congress, at the urging of the Reagan administration, Congress provided funding for the manufacture of binary chemical weapons (sarin artillery shells) from 1987 until 1990, but this was halted after the U.S. and the Soviet Union entered into a bilateral agreement in June 1990.^[55] In the 1990 agreement, the U.S. and Soviet Union agreed to begin destroying their chemical weapons stockpiles before 1993 and to reduce them to no more than 5,000 agent tons each by the end of 2002. The agreement also provided for exchanges of data and inspections of sites to verify destruction.^[58] Following the collapse of the Soviet Union, the U.S.'s Nunn–Lugar Cooperative Threat Reduction program helped eliminate some of the chemical, biological and nuclear stockpiles of the former Soviet Union.^[58]

The United Nations Conference on Disarmament in Geneva in 1980 led to the development of the Chemical Weapons Convention (CWC), a multilateral treaty that prohibited the development, production, stockpiling, and use of chemical weapons, and required the elimination of existing stockpiles.^[59] The treaty expressly prohibited state parties from making reservations (unilateral caveats).^[59] During the Reagan administration and the George H. W. Bush administration, the U.S. participated in the negotiations toward the CWC.^[59] The CWC was concluded on September 3, 1992, and opened for signature on January 13, 1993. The U.S. became one of 87 original state parties to the CWC.^[59] President Bill Clinton submitted it to the U.S. Senate for ratification on November 23, 1993. Ratification was blocked in the Senate for years, largely as a result of opposition from Senator Jesse Helms, the chairman of the Senate Foreign Relations Committee.^[59] On April 24, 1997, the Senate gave its consent to ratification of the CWC by a 74–26 vote (satisfying the required two-thirds majority). The U.S. deposited its instrument of ratification at the United Nations on April 25, 1997, a few days before the CWC entered into force. The U.S. ratification allowed the U.S. to participate in the Organisation for the Prohibition of Chemical Weapons, the organization based in The Hague that oversees implementation of the CWC.^[59]

Upon U.S. ratification of the CWC, the U.S. declared a total of 29,918 tons of chemical weapons, and committed to destroying all of the U.S.'s chemical weapons and bulk agent.^[60] The U.S. was one of eight states to declare a stockpile of chemical weapons and to commit to their safe elimination.^[61] The U.S. committed in the CWC to destroy its entire chemical arsenal within 10 years of the entry into force (i.e., by April 29, 2007),^[60] However, at a 2012 conference,^[62] the parties to the CWC parties agreed to extend the U.S. deadline to 2023.^[60][62] By 2012, stockpiles had been eliminated at seven of the U.S.'s nine chemical weapons depots and 89.75% of the 1997 stockpile was destroyed.^[63] The depots were the Aberdeen Chemical Agent Disposal Facility, Anniston Chemical Disposal Facility, Johnston Atoll, Newport Chemical Agent Disposal Facility, Pine Bluff Chemical Disposal Facility, Tooele Chemical Disposal Facility, Umatilla Chemical Disposal Facility,^[62] and Deseret Chemical Depot.^[63] The U.S. closed each site after the completion of stockpile destruction.^[62] In 2019, the U.S. began to eliminate its chemical-weapon stockpile at the last of the nine U.S. chemical weapons storage facilities: the Blue Grass Army Depot in Kentucky.^[60] By May 2021, the U.S. destroyed all of its Category 2 and Category 3 chemical weapons and 96.52% of its Category 1 chemical weapons.^[61] The U.S. is scheduled to complete the elimination of all its chemical weapons by the September 2023 deadline.^[60]

The U.S. has maintained a "calculated ambiguity" policy that warns potential adversaries that a chemical or biological attack against the U.S. or its allies will prompt a "overwhelming and devastating" response. The policy deliberately leaves open the question of whether the U.S. would respond to a chemical attempt with nuclear retaliation.^[64] Commentators have noted that this policy gives policymakers more flexibility, at the possible cost of decreased strategic unpreparedness.^[64]

Discover more about Chemical weapons destruction related topics

Chemical Weapons Convention

Chemical Weapons Convention

The Chemical Weapons Convention (CWC), officially the Convention on the Prohibition of the Development, Production, Stockpiling and Use of Chemical Weapons and on their Destruction, is an arms control treaty administered by the Organisation for the Prohibition of Chemical Weapons (OPCW), an intergovernmental organization based in The Hague, The Netherlands. The treaty entered into force on 29 April 1997, and prohibits the large-scale use, development, production, stockpiling and transfer of chemical weapons and their precursors, except for very limited purposes. The main obligation of member states under the convention is to effect this prohibition, as well as the destruction of all current chemical weapons. All destruction activities must take place under OPCW verification.

Organisation for the Prohibition of Chemical Weapons

Organisation for the Prohibition of Chemical Weapons

The Organisation for the Prohibition of Chemical Weapons (OPCW) is an intergovernmental organisation and the implementing body for the Chemical Weapons Convention (CWC), which entered into force on 29 April 1997. The OPCW, with its 193 member states, has its seat in The Hague, Netherlands; it oversees the global endeavour for the permanent and verifiable elimination of chemical weapons.

United Nations

United Nations

The United Nations (UN), particularly informally also referred to as the United Nations Organization (UNO), is an intergovernmental organization whose stated purposes are to maintain international peace and security, develop friendly relations among nations, achieve international cooperation, and be a centre for harmonizing the actions of nations. It is the world's largest and most familiar international organization. The UN is headquartered on international territory in New York City, and has other main offices in Geneva, Nairobi, Vienna, and The Hague.

Second Sino-Japanese War

Second Sino-Japanese War

The Second Sino-Japanese War (1937–1945) or War of Resistance was a military conflict primarily between the Republic of China and the Empire of Japan. The war made up the Chinese theater of the wider Pacific Theater of the Second World War. The beginning of the war is conventionally dated to the Marco Polo Bridge Incident on 7 July 1937, when a dispute between Japanese and Chinese troops in Peking escalated into a full-scale invasion. Some Chinese historians consider the start of the war as the Japanese invasion of Manchuria on 18 September 1931. China was aided by the Soviet Union, the United Kingdom, the United States, and Nazi Germany before its alliance with Japan. Around 20 million people, mostly civilians, were killed.

Mainland China

Mainland China

"Mainland China" is a geopolitical term defined as the territory governed by the People's Republic of China, excluding dependent territories of the PRC, and other territories within Greater China. By convention, the territories that fall outside of the Chinese mainland include:Hong Kong, a quasi-dependent territory under PRC rule that is officially designated a "Special Administrative Region of the PRC" Macau, a quasi-dependent territory under PRC rule that is officially designated a "Special Administrative Region of the PRC" Territories ruled by the Republic of China, including the island of Taiwan, the Penghu (Pescadores) islands in the Taiwan Strait, and the islands Kinmen, Matsu, and Wuqiu (Kinmen) offshore of Fujian.

Lewisite

Lewisite

Lewisite (L) (A-243) is an organoarsenic compound. It was once manufactured in the U.S., Japan, Germany and the Soviet Union for use as a chemical weapon, acting as a vesicant and lung irritant. Although the substance is colorless and odorless in its pure form, impure samples of lewisite are a yellow, brown, violet-black, green, or amber oily liquid with a distinctive odor that has been described as similar to geraniums.

Sarin

Sarin

Sarin is an extremely toxic synthetic organophosphorus compound. A colourless, odourless liquid, it is used as a chemical weapon due to its extreme potency as a nerve agent. Exposure is lethal even at very low concentrations, where death can occur within one to ten minutes after direct inhalation of a lethal dose, due to suffocation from respiratory paralysis, unless antidotes are quickly administered. People who absorb a non-lethal dose and do not receive immediate medical treatment may suffer permanent neurological damage.

Soman

Soman

Soman is an extremely toxic chemical substance. It is a nerve agent, interfering with normal functioning of the mammalian nervous system by inhibiting the enzyme cholinesterase. It is an inhibitor of both acetylcholinesterase and butyrylcholinesterase. As a chemical weapon, it is classified as a weapon of mass destruction by the United Nations according to UN Resolution 687. Its production is strictly controlled, and stockpiling is outlawed by the Chemical Weapons Convention of 1993 where it is classified as a Schedule 1 substance. Soman was the third of the so-called G-series nerve agents to be discovered along with GA (tabun), GB (sarin), and GF (cyclosarin).

VX (nerve agent)

VX (nerve agent)

VX is an extremely toxic synthetic chemical compound in the organophosphorus class, specifically, a thiophosphonate. In the class of nerve agents, it was developed for military use in chemical warfare after translation of earlier discoveries of organophosphate toxicity in pesticide research. In recent years, VX was found to be the agent used in the assassination of Kim Jong-nam. In its pure form, VX is an oily, relatively non-volatile liquid that is amber-like in colour. Because of its low volatility, VX persists in environments where it is dispersed.

Richard Nixon

Richard Nixon

Richard Milhous Nixon was the 37th president of the United States, serving from 1969 to 1974. A member of the Republican Party, he previously served as a representative and senator from California and was the 36th vice president from 1953 to 1961 under President Dwight D. Eisenhower. His five years in the White House saw reduction of U.S. involvement in the Vietnam War, détente with the Soviet Union and China, the first crewed Moon landings, and the establishment of the Environmental Protection Agency and Occupational Safety and Health Administration. Nixon's second term ended early, when he became the only president to resign from office, as a result of the Watergate scandal.

Statement on Chemical and Biological Defense Policies and Programs

Statement on Chemical and Biological Defense Policies and Programs

The "Statement on Chemical and Biological Defense Policies and Programs" was a speech delivered on November 25, 1969, by U.S. President Richard Nixon. In the speech, Nixon announced the end of the U.S. offensive biological weapons program and reaffirmed a no-first-use policy for chemical weapons. The statement excluded toxins, herbicides and riot-control agents as they were not chemical and biological weapons, though herbicides and toxins were both later banned. The decision to ban biological weapons was influenced by a number of domestic and international issues.

Herbicidal warfare

Disabled children in Vietnam, most of them impacted by Agent Orange, 2004

Although herbicidal warfare use chemical substances, its main purpose is to disrupt agricultural food production and/or to destroy plants which provide cover or concealment to the enemy.

The use of herbicides by the U.S. military during the Vietnam War has left tangible, long-term impacts upon the Vietnamese people and U.S. veterans of the war.^[65][66] The government of Vietnam says that around 24% of the forests of Southern Vietnam were defoliated and up to four million people in Vietnam were exposed to Agent Orange. They state that as many as three million people have developed illness because of Agent Orange while the Red Cross of Vietnam estimates that up to one million people were disabled or have health problems associated with Agent Orange. The United States government has described these figures as unreliable.^[67][68][69] During the war, the U.S. fought the North Vietnamese and their allies in Laos and Cambodia, dropping large quantities of Agent Orange in each of those countries. According on one estimate, the U.S. dropped 475,500 US gallons (1,800,000 L) of Agent Orange in Laos and 40,900 US gallons (155,000 L) in Cambodia.^[70][71][72] Because Laos and Cambodia were officially neutral during the Vietnam War, the U.S. attempted to keep secret its military involvement in these countries. The U.S. has stated that Agent Orange was not widely used and therefore hasn't offered assistance to affected Cambodians or Laotians, and limits benefits American veterans and CIA personnel who were stationed there.^[71][73]

Anti-livestock

During the Mau Mau Uprising in 1952, the poisonous latex of the African milk bush was used to kill cattle.^[74]

Discover more about Anti-agriculture related topics

Herbicidal warfare

Herbicidal warfare

Herbicidal warfare is the use of substances primarily designed to destroy the plant-based ecosystem of an area. Although herbicidal warfare use chemical substances, its main purpose is to disrupt agricultural food production and/or to destroy plants which provide cover or concealment to the enemy, not to asphyxiate or poison humans and/or destroy human-made structures. Herbicidal warfare has been forbidden by the Environmental Modification Convention since 1978, which bans "any technique for changing the composition or structure of the Earth's biota".

Vietnam

Vietnam

Vietnam or Viet Nam, officially the Socialist Republic of Vietnam (SRV), is a country in Southeast Asia. It is located at the eastern edge of mainland Southeast Asia, with an area of 331,212 square kilometres (127,882 sq mi) and population of 99 million, making it the world's fifteenth-most populous country. Vietnam borders China to the north, and Laos and Cambodia to the west. It shares maritime borders with Thailand through the Gulf of Thailand, and the Philippines, Indonesia, and Malaysia through the South China Sea. Its capital is Hanoi and its largest city is Ho Chi Minh City.

Agent Orange

Agent Orange

Agent Orange is a chemical herbicide and defoliant, one of the "tactical use" Rainbow Herbicides. It was used by the U.S. military as part of its herbicidal warfare program, Operation Ranch Hand, during the Vietnam War from 1961 to 1971. It is a mixture of equal parts of two herbicides, 2,4,5-T and 2,4-D. In addition to its damaging environmental effects, traces of dioxin found in the mixture have caused major health problems for many individuals who were exposed, and their offspring.

Chemical substance

Chemical substance

A chemical substance is a form of matter having constant chemical composition and characteristic properties. Some references add that chemical substance cannot be separated into its constituent elements by physical separation methods, i.e., without breaking chemical bonds. Chemical substances can be simple substances, chemical compounds, or alloys.

Herbicide

Herbicide

Herbicides, also commonly known as weed killers, are substances used to control undesired plants, also known as weeds. Selective herbicides control specific weed species while leaving the desired crop relatively unharmed, while non-selective herbicides can be used to clear waste ground, industrial and construction sites, railways and railway embankments as they kill all plant material with which they come into contact. Apart from selective/non-selective, other important distinctions include persistence, means of uptake, and mechanism of action. Historically, products such as common salt and other metal salts were used as herbicides, however, these have gradually fallen out of favor, and in some countries, a number of these are banned due to their persistence in soil, and toxicity and groundwater contamination concerns. Herbicides have also been used in warfare and conflict.

United States Armed Forces

United States Armed Forces

The United States Armed Forces are the military forces of the United States. The armed forces consists of six service branches: the Army, Marine Corps, Navy, Air Force, Space Force, and Coast Guard. All six armed services are among the eight uniformed services of the United States.

Vietnam War

Vietnam War

The Vietnam War was a conflict in Vietnam, Laos, and Cambodia from 1 November 1955 to the fall of Saigon on 30 April 1975. It was the second of the Indochina Wars and was officially fought between North Vietnam and South Vietnam. The north was supported by the Soviet Union, China, and other communist states, while the south was supported by the United States and other anti-communist allies. The war is widely considered to be a Cold War-era proxy war. It lasted almost 20 years, with direct U.S. involvement ending in 1973. The conflict also spilled over into neighboring states, exacerbating the Laotian Civil War and the Cambodian Civil War, which ended with all three countries becoming communist states by 1975.

Effects of Agent Orange on the Vietnamese people

Effects of Agent Orange on the Vietnamese people

Agent Orange is a herbicide, classified as a defoliant, that was used most notably by the U.S. military during the Vietnam War. Its primary purpose was strategic deforestation, destroying the forest cover and food resources necessary for the implementation and sustainability of the North Vietnamese style of guerilla warfare. The U.S. Agent Orange usage reached an apex during Operation Ranch Hand, in which the material was sprayed over 4.5 million acres of land in Vietnam from 1961 to 1971.

Laotian Civil War

Laotian Civil War

The Laotian Civil War (1959–1975) was a civil war in Laos which was waged between the Communist Pathet Lao and the Royal Lao Government from 23 May 1959 to 2 December 1975. It is associated with the Cambodian Civil War and the Vietnam War, with both sides receiving heavy external support in a proxy war between the global Cold War superpowers. It is called the Secret War among the American CIA Special Activities Center, and Hmong and Mien veterans of the conflict.

Cambodian Civil War

Cambodian Civil War

The Cambodian Civil War was a civil war in Cambodia fought between the forces of the Communist Party of Kampuchea against the government forces of the Kingdom of Cambodia and, after October 1970, the Khmer Republic, which had succeeded the kingdom.

Latex

Latex

Latex is an emulsion of polymer microparticles in water. Latexes are found in nature, but synthetic latexes are common as well.

Euphorbia grantii

Euphorbia grantii

Euphorbia grantii is a species of succulent plant in the family Euphorbiaceae.