Biodiesel

Biodiesel sample

Blends of biodiesel and conventional hydrocarbon-based diesel are most commonly distributed for use in the retail diesel fuel marketplace. Much of the world uses a system known as the "B" factor to state the amount of biodiesel in any fuel mix:^[7]

• 100% biodiesel is referred to as B100
• 20% biodiesel, 80% petrodiesel is labeled B20^[4]
• 7% biodiesel, 93% petrodiesel is labeled B7
• 5% biodiesel, 95% petrodiesel is labeled B5
• 2% biodiesel, 98% petrodiesel is labeled B2

Blends of 20% biodiesel and lower can be used in diesel equipment with no, or only minor modifications,^[8] although certain manufacturers do not extend warranty coverage if equipment is damaged by these blends. The B6 to B20 blends are covered by the ASTM D7467 specification.^[9] Biodiesel can also be used in its pure form (B100), but may require certain engine modifications to avoid maintenance and performance problems.^[10] Blending B100 with petroleum diesel may be accomplished by:

• Mixing in tanks at manufacturing point prior to delivery to tanker truck
• Splash mixing in the tanker truck (adding specific percentages of biodiesel and petroleum diesel)
• In-line mixing, two components arrive at tanker truck simultaneously.
• Metered pump mixing, petroleum diesel and biodiesel meters are set to X total volume,

Rudolf Diesel

Transesterification of a vegetable oil was conducted as early as 1853 by Patrick Duffy, four decades before the first diesel engine became functional.^[11][12] Earlier processes for making lamp oil, were patented (1810, Prague) but not published as peer reviewed publications. Rudolf Diesel's prime model, a single 10 ft (3.05 m) iron cylinder with a flywheel at its base, ran on its own power for the first time in Augsburg, Germany, on 10 August 1893 running on nothing but peanut oil. In remembrance of this event, 10 August has been declared "International Biodiesel Day".^[13]

It is often reported that Diesel designed his engine to run on peanut oil, but this is not the case. Diesel stated in his published papers, "at the Paris Exhibition in 1900 (Exposition Universelle) there was shown by the Otto Company a small Diesel engine, which, at the request of the French government ran on arachide (earth-nut or pea-nut) oil (see biodiesel), and worked so smoothly that only a few people were aware of it. The engine was constructed for using mineral oil, and was then worked on vegetable oil without any alterations being made. The French Government at the time thought of testing the applicability to power production of the Arachide, or earth-nut, which grows in considerable quantities in their African colonies, and can easily be cultivated there." Diesel himself later conducted related tests and appeared supportive of the idea.^[14] In a 1912 speech Diesel said, "the use of vegetable oils for engine fuels may seem insignificant today but such oils may become, in the course of time, as important as petroleum and the coal-tar products of the present time."

Despite the widespread use of petroleum-derived diesel fuels, interest in vegetable oils as fuels for internal combustion engines was reported in several countries during the 1920s and 1930s and later during World War II. Belgium, France, Italy, the United Kingdom, Portugal, Germany, Brazil, Argentina, Japan and China were reported to have tested and used vegetable oils as diesel fuels during this time. Some operational problems were reported due to the high viscosity of vegetable oils compared to petroleum diesel fuel, which results in poor atomization of the fuel in the fuel spray and often leads to deposits and coking of the injectors, combustion chamber and valves. Attempts to overcome these problems included heating of the vegetable oil, blending it with petroleum-derived diesel fuel or ethanol, pyrolysis and cracking of the oils.

On 31 August 1937, G. Chavanne of the University of Brussels (Belgium) was granted a patent for a "Procedure for the transformation of vegetable oils for their uses as fuels" (fr. "Procédé de Transformation d’Huiles Végétales en Vue de Leur Utilisation comme Carburants") Belgian Patent 422,877. This patent described the alcoholysis (often referred to as transesterification) of vegetable oils using ethanol (and mentions methanol) in order to separate the fatty acids from the glycerol by replacing the glycerol with short linear alcohols. This appears to be the first account of the production of what is known as "biodiesel" today.^[15] This is similar (copy) to the patented methods used in the 18th century to make lamp-oil, and may be inspired by some old historical oil lamps, in some places.

More recently, in 1977, Brazilian scientist Expedito Parente invented and submitted for patent, the first industrial process for the production of biodiesel.^[16] This process is classified as biodiesel by international norms, conferring a "standardized identity and quality. No other proposed biofuel has been validated by the motor industry."^[17] As of 2010, Parente's company Tecbio is working with Boeing and NASA to certify bioquerosene (bio-kerosene), another product produced and patented by the Brazilian scientist.^[18]

Research into the use of transesterified sunflower oil, and refining it to diesel fuel standards, was initiated in South Africa in 1979. By 1983, the process for producing fuel-quality, engine-tested biodiesel was completed and published internationally.^[19] An Austrian company, Gaskoks, obtained the technology from the South African Agricultural Engineers; the company erected the first biodiesel pilot plant in November 1987, and the first industrial-scale plant in April 1989 (with a capacity of 30,000 tons of rapeseed per annum).

Throughout the 1990s, plants were opened in many European countries, including the Czech Republic, Germany and Sweden. France launched local production of biodiesel fuel (referred to as diester) from rapeseed oil, which is mixed into regular diesel fuel at a level of 5%, and into the diesel fuel used by some captive fleets (e.g. public transportation) at a level of 30%. Renault, Peugeot and other manufacturers have certified truck engines for use with up to that level of partial biodiesel; experiments with 50% biodiesel are underway. During the same period, nations in other parts of the world also saw local production of biodiesel starting up: by 1998, the Austrian Biofuels Institute had identified 21 countries with commercial biodiesel projects. 100% biodiesel is now available at many normal service stations across Europe.

Discover more about Historical background related topics

Diesel engine

Diesel engine

The diesel engine, named after Rudolf Diesel, is an internal combustion engine in which ignition of the fuel is caused by the elevated temperature of the air in the cylinder due to mechanical compression; thus, the diesel engine is called a compression-ignition engine. This contrasts with engines using spark plug-ignition of the air-fuel mixture, such as a petrol engine or a gas engine.

Oil lamp

Oil lamp

An oil lamp is a lamp used to produce light continuously for a period of time using an oil-based fuel source. The use of oil lamps began thousands of years ago and continues to this day, although their use is less common in modern times. They work in the same way as a candle but with fuel that is liquid at room temperature, so that a container for the oil is required. A textile wick drops down into the oil, and is lit at the end, burning the oil as it is drawn up the wick.

Augsburg

Augsburg

Augsburg is a city in Swabia, Bavaria, Germany, around 50 kilometres (31 mi) west of Bavarian capital Munich. It is a university town and regional seat of the Regierungsbezirk Schwaben with an impressive Altstadt. Augsburg is an urban district and home to the institutions of the Landkreis Augsburg. It is the third-largest city in Bavaria with a population of 300,000 inhabitants, with 885,000 in its metropolitan area.

Peanut oil

Peanut oil

Peanut oil, also known as groundnut oil or arachis oil, is a vegetable oil derived from peanuts. The oil usually has a mild or neutral flavor but, if made with roasted peanuts, has a stronger peanut flavor and aroma. It is often used in American, Chinese, Indian, African and Southeast Asian cuisine, both for general cooking, and in the case of roasted oil, for added flavor. Peanut oil has a high smoke point relative to many other cooking oils, so it is commonly used for frying foods.

Exposition Universelle (1900)

Exposition Universelle (1900)

The Exposition Universelle of 1900, better known in English as the 1900 Paris Exposition, was a world's fair held in Paris, France, from 14 April to 12 November 1900, to celebrate the achievements of the past century and to accelerate development into the next. It was held at the esplanade of Les Invalides, the Champ de Mars, the Trocadéro and at the banks of the Seine between them, with an additional section in the Bois de Vincennes, and it was visited by more than 50 million people. Many international congresses and other events were held within the framework of the exposition, including the 1900 Summer Olympics.

Belgium

Belgium

Belgium, officially the Kingdom of Belgium, is a country in Northwestern Europe. The country is bordered by the Netherlands to the north, Germany to the east, Luxembourg to the southeast, France to the southwest, and the North Sea to the northwest. It covers an area of 30,528 km2 (11,787 sq mi) and has a population of more than 11.5 million, making it the 22nd most densely populated country in the world and the 6th most densely populated country in Europe, with a density of 376/km2 (970/sq mi). Belgium is part of an area known as the Low Countries, historically a somewhat larger region than the Benelux group of states, as it also included parts of northern France. The capital and largest city is Brussels; other major cities are Antwerp, Ghent, Charleroi, Liège, Bruges, Namur, and Leuven.

Portugal

Portugal

Portugal, officially the Portuguese Republic, is a country located on the Iberian Peninsula, in southwestern Europe, and whose territory also includes the Atlantic archipelagos of the Azores and Madeira. It features the westernmost point in continental Europe, and its Iberian portion is bordered to the west and south by the Atlantic Ocean and to the north and east by Spain, the sole country to have a land border with Portugal. Its two archipelagos form two autonomous regions with their own regional governments. Lisbon is the capital and largest city by population.

Brazil

Brazil

Brazil, officially the Federative Republic of Brazil, is the largest country in South America and in Latin America. At 8.5 million square kilometers (3,300,000 sq mi) and with over 217 million people, Brazil is the world's fifth-largest country by area and the seventh most populous. Its capital is Brasília, and its most populous city is São Paulo. The federation is composed of the union of the 26 states and the Federal District. It is the only country in the Americas to have Portuguese as an official language. It is one of the most multicultural and ethnically diverse nations, due to over a century of mass immigration from around the world, and the most populous Roman Catholic-majority country.

Argentina

Argentina

Argentina, officially the Argentine Republic, is a country in the southern half of South America. Argentina covers an area of 2,780,400 km2 (1,073,500 sq mi), making it the second-largest country in South America after Brazil, the fourth-largest country in the Americas, and the eighth-largest country in the world. It shares the bulk of the Southern Cone with Chile to the west, and is also bordered by Bolivia and Paraguay to the north, Brazil to the northeast, Uruguay and the South Atlantic Ocean to the east, and the Drake Passage to the south. Argentina is a federal state subdivided into twenty-three provinces, and one autonomous city, which is the federal capital and largest city of the nation, Buenos Aires. The provinces and the capital have their own constitutions, but exist under a federal system. Argentina claims sovereignty over the Falkland Islands, South Georgia and the South Sandwich Islands, and a part of Antarctica.

Aerosol

Aerosol

An aerosol is a suspension of fine solid particles or liquid droplets in air or another gas. Aerosols can be natural or anthropogenic. Examples of natural aerosols are fog or mist, dust, forest exudates, and geyser steam. Examples of anthropogenic aerosols include particulate air pollutants, mist from the discharge at hydroelectric dams, irrigation mist, perfume from atomizers, smoke, dust, steam from a kettle, sprayed pesticides, and medical treatments for respiratory illnesses. When a person inhales the contents of a vape pen or e-cigarette, they are inhaling an anthropogenic aerosol.

Fluid catalytic cracking

Fluid catalytic cracking

Fluid Catalytic Cracking (FCC) is the conversion process used in petroleum refineries to convert the high-boiling point, high-molecular weight hydrocarbon fractions of petroleum into gasoline, olefinic gases, and other petroleum products. The cracking of petroleum hydrocarbons was originally done by thermal cracking, now virtually replaced by catalytic cracking, which yields greater volumes of high octane rating gasoline; and produces by-product gases, with more carbon-carbon double bonds, that are of greater economic value than the gases produced by thermal cracking.

Boeing

Boeing

The Boeing Company is an American multinational corporation that designs, manufactures, and sells airplanes, rotorcraft, rockets, satellites, telecommunications equipment, and missiles worldwide. The company also provides leasing and product support services. Boeing is among the largest global aerospace manufacturers; it is the third-largest defense contractor in the world based on 2020 revenue, and is the largest exporter in the United States by dollar value. Boeing stock is included in the Dow Jones Industrial Average. Boeing is incorporated in Delaware.

The color of biodiesel ranges from clear to golden to dark brown, depending on the production method and the feedstock used to make the fuel. This also changes the resulting fuel properties.^[20] In general, biodiesel is slightly miscible with water, has a high boiling point and low vapor pressure. The flash point of biodiesel can exceed 130 °C (266 °F),^[21] significantly higher than that of petroleum diesel which may be as low as 52 °C (126 °F).^[22][23] Biodiesel has a density around ~0.88 g/cm³, higher than petrodiesel (~0.85 g/cm³).^[22][23]

The calorific value of biodiesel is about 37.27 MJ/kg.^[24] This is 9% lower than regular Number 2 petrodiesel. Variations in biodiesel energy density is more dependent on the feedstock used than the production process. Still, these variations are less than for petrodiesel.^[25] It has been claimed biodiesel gives better lubricity and more complete combustion thus increasing the engine energy output and partially compensating for the higher energy density of petrodiesel.^[26]

Biodiesel also contains virtually no sulfur^[27] and although lacking sulfur compounds that in petrodiesel provide much of the lubricity, it has promising lubricating properties and cetane ratings compared to low sulfur diesel fuels and often serves as an additive to ultra-low-sulfur diesel (ULSD) fuel to aid with lubrication.^[28] Biodiesel Fuels with higher lubricity may increase the usable life of high-pressure fuel injection equipment that relies on the fuel for its lubrication. Depending on the engine, this might include high pressure injection pumps, pump injectors (also called unit injectors) and fuel injectors.

Older diesel Mercedes are popular for running on biodiesel.

Discover more about Properties related topics

Boiling point

Boiling point

The boiling point of a substance is the temperature at which the vapor pressure of a liquid equals the pressure surrounding the liquid and the liquid changes into a vapor.

Vapor pressure

Vapor pressure

Vapor pressure is defined as the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phases at a given temperature in a closed system. The equilibrium vapor pressure is an indication of a liquid's thermodynamic tendency to evaporate. It relates to the balance of particles escaping from the liquid in equilibrium with those in a coexisting vapor phase. A substance with a high vapor pressure at normal temperatures is often referred to as volatile. The pressure exhibited by vapor present above a liquid surface is known as vapor pressure. As the temperature of a liquid increases, the attractive interactions between liquid molecules become less significant in comparison to the entropy of those molecules in the gas phase, increasing the vapor pressure. Thus, liquids with strong intermolecular interactions are likely to have smaller vapor pressures, with the reverse true for weaker interactions.

Flash point

Flash point

The flash point of a material is the "lowest liquid temperature at which, under certain standardized conditions, a liquid gives off vapours in a quantity such as to be capable of forming an ignitable vapour/air mixture".

Cetane number

Cetane number

Cetane number is an indicator of the combustion speed of diesel fuel and compression needed for ignition. It plays a similar role for diesel as octane rating does for gasoline. The CN is an important factor in determining the quality of diesel fuel, but not the only one; other measurements of diesel fuel's quality include energy content, density, lubricity, cold-flow properties and sulphur content.

Ultra-low-sulfur diesel

Ultra-low-sulfur diesel

Ultra-low-sulfur diesel (ULSD) is diesel fuel with substantially lowered sulfur content. Since 2006, almost all of the petroleum-based diesel fuel available in Europe and North America has been of a ULSD type.

Targray Biofuels railcar transporting Biodiesel.

Biodiesel can be used in pure form (B100) or may be blended with petroleum diesel at any concentration in most injection pump diesel engines. New extreme high-pressure (29,000 psi) common rail engines have strict factory limits of B5 or B20, depending on manufacturer.^[29] Biodiesel has different solvent properties from petrodiesel, and will degrade natural rubber gaskets and hoses in vehicles (mostly vehicles manufactured before 1992), although these tend to wear out naturally and most likely will have already been replaced with FKM, which is nonreactive to biodiesel. Biodiesel has been known to break down deposits of residue in the fuel lines where petrodiesel has been used.^[30] As a result, fuel filters may become clogged with particulates if a quick transition to pure biodiesel is made. Therefore, it is recommended to change the fuel filters on engines and heaters shortly after first switching to a biodiesel blend.^[31]

Distribution

Since the passage of the Energy Policy Act of 2005, biodiesel use has been increasing in the United States.^[32] In the UK, the Renewable Transport Fuel Obligation obliges suppliers to include 5% renewable fuel in all transport fuel sold in the UK by 2010. For road diesel, this effectively means 5% biodiesel (B5).

Vehicular use and manufacturer acceptance

In 2005, Chrysler (then part of DaimlerChrysler) released the Jeep Liberty CRD diesels from the factory into the European market with 5% biodiesel blends, indicating at least partial acceptance of biodiesel as an acceptable diesel fuel additive.^[33] In 2007, DaimlerChrysler indicated its intention to increase warranty coverage to 20% biodiesel blends if biofuel quality in the United States can be standardized.^[34]

The Volkswagen Group has released a statement indicating that several of its vehicles are compatible with B5 and B100 made from rape seed oil and compatible with the EN 14214 standard. The use of the specified biodiesel type in its cars will not void any warranty.^[35]

Mercedes Benz does not allow diesel fuels containing greater than 5% biodiesel (B5) due to concerns about "production shortcomings".^[36] Any damages caused by the use of such non-approved fuels will not be covered by the Mercedes-Benz Limited Warranty.

Starting in 2004, the city of Halifax, Nova Scotia decided to update its bus system to allow the fleet of city buses to run entirely on a fish-oil based biodiesel. This caused the city some initial mechanical issues, but after several years of refining, the entire fleet had successfully been converted.^[37][38][39]

In 2007, McDonald's of UK announced it would start producing biodiesel from the waste oil byproduct of its restaurants. This fuel would be used to run its fleet.^[40]

The 2014 Chevy Cruze Clean Turbo Diesel, direct from the factory, will be rated for up to B20 (blend of 20% biodiesel / 80% regular diesel) biodiesel compatibility^[41]

Railway usage

Biodiesel locomotive and its external fuel tank at Mount Washington Cog Railway

British train operating company Virgin Trains West Coast claimed to have run the UK's first "biodiesel train", when a Class 220 was converted to run on 80% petrodiesel and 20% biodiesel.^[42][43]

The British Royal Train on 15 September 2007 completed its first ever journey run on 100% biodiesel fuel supplied by Green Fuels Ltd. Prince Charles and Green Fuels managing director James Hygate were the first passengers on a train fueled entirely by biodiesel fuel. Since 2007, the Royal Train has operated successfully on B100 (100% biodiesel).^[44] A government white paper also proposed converting large portions of the UK railways to biodiesel but the proposal was subsequently dropped in favour of further electrification.^[45]

Similarly, a state-owned short-line railroad in Eastern Washington ran a test of a 25% biodiesel / 75% petrodiesel blend during the summer of 2008, purchasing fuel from a biodiesel producer sited along the railroad tracks.^[46] The train will be powered by biodiesel made in part from canola grown in agricultural regions through which the short line runs.

Also in 2007, Disneyland began running the park trains on B98 (98% biodiesel). The program was discontinued in 2008 due to storage issues, but in January 2009, it was announced that the park would then be running all trains on biodiesel manufactured from its own used cooking oils. This is a change from running the trains on soy-based biodiesel.^[47]

In 2007, the historic Mt. Washington Cog Railway added the first biodiesel locomotive to its all-steam locomotive fleet. The fleet has climbed up the western slopes of Mount Washington in New Hampshire since 1868 with a peak vertical climb of 37.4 degrees.^[48]

On 8 July 2014,^[49] the then Indian Railway Minister D.V. Sadananda Gowda announced in Railway Budget that 5% bio-diesel will be used in Indian Railways' Diesel Engines.^[50]

As a heating oil

Biodiesel can also be used as a heating fuel in domestic and commercial boilers, a mix of heating oil and biofuel which is standardized and taxed slightly differently from diesel fuel used for transportation. Bioheat fuel is a proprietary blend of biodiesel and traditional heating oil. Bioheat is a registered trademark of the National Biodiesel Board [NBB] and the National Oilheat Research Alliance [NORA] in the United States, and Columbia Fuels in Canada.^[51] Heating biodiesel is available in various blends. ASTM 396 recognizes blends of up to 5 percent biodiesel as equivalent to pure petroleum heating oil. Blends of higher levels of up to 20% biofuel are used by many consumers. Research is underway to determine whether such blends affect performance.

Older furnaces may contain rubber parts that would be affected by biodiesel's solvent properties, but can otherwise burn biodiesel without any conversion required. Care must be taken, given that varnishes left behind by petrodiesel will be released and can clog pipes—fuel filtering and prompt filter replacement is required. Another approach is to start using biodiesel as a blend, and decreasing the petroleum proportion over time can allow the varnishes to come off more gradually and be less likely to clog. Due to biodiesel's strong solvent properties, the furnace is cleaned out and generally becomes more efficient.^[52]

A law passed under Massachusetts Governor Deval Patrick requires all home heating diesel in that state to be 2% biofuel by July 1, 2010, and 5% biofuel by 2013.^[53] New York City has passed a similar law.

Cleaning oil spills

With 80–90% of oil spill costs invested in shoreline cleanup, there is a search for more efficient and cost-effective methods to extract oil spills from the shorelines.^[54] Biodiesel has displayed its capacity to significantly dissolve crude oil, depending on the source of the fatty acids. In a laboratory setting, oiled sediments that simulated polluted shorelines were sprayed with a single coat of biodiesel and exposed to simulated tides.^[55] Biodiesel is an effective solvent to oil due to its methyl ester component, which considerably lowers the viscosity of the crude oil. Additionally, it has a higher buoyancy than crude oil, which later aids in its removal. As a result, 80% of oil was removed from cobble and fine sand, 50% in coarse sand, and 30% in gravel. Once the oil is liberated from the shoreline, the oil-biodiesel mixture is manually removed from the water surface with skimmers. Any remaining mixture is easily broken down due to the high biodegradability of biodiesel, and the increased surface area exposure of the mixture.

Biodiesel in generators

Biodiesel is also used in rental generators

In 2001, UC Riverside installed a 6-megawatt backup power system that is entirely fueled by biodiesel. Backup diesel-fueled generators allow companies to avoid damaging blackouts of critical operations at the expense of high pollution and emission rates. By using B100, these generators were able to essentially eliminate the byproducts that result in smog, ozone, and sulfur emissions.^[56] The use of these generators in residential areas around schools, hospitals, and the general public result in substantial reductions in poisonous carbon monoxide and particulate matter.^[57]

Fuel efficiency

The power output of biodiesel depends on its blend, quality, and load conditions under which the fuel is burnt. The thermal efficiency for example of B100 as compared to B20 will vary due to the differing energy content of the various blends. Thermal efficiency of a fuel is based in part on fuel characteristics such as: viscosity, specific density, and flash point; these characteristics will change as the blends as well as the quality of biodiesel varies. The American Society for Testing and Materials has set standards in order to judge the quality of a given fuel sample.^[58]

One study found that the brake thermal efficiency of B40 was superior to traditional petroleum counterpart at higher compression ratios (this higher brake thermal efficiency was recorded at compression ratios of 21:1). It was noted that, as the compression ratios increased, the efficiency of all fuel types – as well as blends being tested – increased; though it was found that a blend of B40 was the most economical at a compression ratio of 21:1 over all other blends. The study implied that this increase in efficiency was due to fuel density, viscosity, and heating values of the fuels.^[59]

Combustion

Fuel systems on some modern diesel engines were not designed to accommodate biodiesel, while many heavy duty engines are able to run with biodiesel blends up to B20.^[4] Traditional direct injection fuel systems operate at roughly 3,000 psi at the injector tip while the modern common rail fuel system operates upwards of 30,000 PSI at the injector tip. Components are designed to operate at a great temperature range, from below freezing to over 1,000 °F (560 °C). Diesel fuel is expected to burn efficiently and produce as few emissions as possible. As emission standards are being introduced to diesel engines the need to control harmful emissions is being designed into the parameters of diesel engine fuel systems. The traditional inline injection system is more forgiving to poorer quality fuels as opposed to the common rail fuel system. The higher pressures and tighter tolerances of the common rail system allows for greater control over atomization and injection timing. This control of atomization as well as combustion allows for greater efficiency of modern diesel engines as well as greater control over emissions. Components within a diesel fuel system interact with the fuel in a way to ensure efficient operation of the fuel system and so the engine. If an out-of-specification fuel is introduced to a system that has specific parameters of operation, then the integrity of the overall fuel system may be compromised. Some of these parameters such as spray pattern and atomization are directly related to injection timing.^[60]

One study found that during atomization, biodiesel and its blends produced droplets greater in diameter than the droplets produced by traditional petrodiesel. The smaller droplets were attributed to the lower viscosity and surface tension of traditional diesel fuel. It was found that droplets at the periphery of the spray pattern were larger in diameter than the droplets at the center. This was attributed to the faster pressure drop at the edge of the spray pattern; there was a proportional relationship between the droplet size and the distance from the injector tip. It was found that B100 had the greatest spray penetration, this was attributed to the greater density of B100.^[61] Having a greater droplet size can lead to inefficiencies in the combustion, increased emissions, and decreased horse power. In another study it was found that there is a short injection delay when injecting biodiesel. This injection delay was attributed to the greater viscosity of Biodiesel. It was noted that the higher viscosity and the greater cetane rating of biodiesel over traditional petrodiesel lead to poor atomization, as well as mixture penetration with air during the ignition delay period.^[62] Another study noted that this ignition delay may aid in a decrease of NO_x emission.^[63]

Emissions

Emissions are inherent to the combustion of diesel fuels that are regulated by the U.S. Environmental Protection Agency (E.P.A.). As these emissions are a byproduct of the combustion process, in order to ensure E.P.A. compliance a fuel system must be capable of controlling the combustion of fuels as well as the mitigation of emissions. There are a number of new technologies being phased in to control the production of diesel emissions. The exhaust gas recirculation system, E.G.R., and the diesel particulate filter, D.P.F., are both designed to mitigate the production of harmful emissions.^[64]

The feedstock used to make the biodiesel fuel can significantly alter the resulting exhaust gas and particulate matter emissions,^[65][66] even when blended with commercial diesel fuel.^[67] A study performed by the Chonbuk National University concluded that a B30 biodiesel blend reduced carbon monoxide emissions by approximately 83% and particulate matter emissions by roughly 33%. NO_x emissions, however, were found to increase without the application of an E.G.R. system. The study also concluded that, with E.G.R, a B20 biodiesel blend considerably reduced the emissions of the engine.^[68] Additionally, analysis by the California Air Resources Board found that biodiesel had the lowest carbon emissions of the fuels tested, those being ultra-low-sulfur diesel, gasoline, corn-based ethanol, compressed natural gas, and five types of biodiesel from varying feedstocks. Their conclusions also showed great variance in carbon emissions of biodiesel based on the feedstock used. Of soy, tallow, canola, corn, and used cooking oil, soy showed the highest carbon emissions, while used cooking oil produced the lowest.^[69]

While studying the effect of biodiesel on diesel particulate filters, it was found that though the presence of sodium and potassium carbonates aided in the catalytic conversion of ash, as the diesel particulates are catalyzed, they may congregate inside the D.P.F. and so interfere with the clearances of the filter. This may cause the filter to clog and interfere with the regeneration process.^[70] In a study on the impact of E.G.R. rates with blends of jathropa biodiesel it was shown that there was a decrease in fuel efficiency and torque output due to the use of biodiesel on a diesel engine designed with an E.G.R. system. It was found that CO and CO₂ emissions increased with an increase in exhaust gas recirculation but NO_x levels decreased. The opacity level of the jathropa blends was in an acceptable range, where traditional diesel was out of acceptable standards. It was shown that a decrease in Nox emissions could be obtained with an E.G.R. system. This study showed an advantage over traditional diesel within a certain operating range of the E.G.R. system.^[71]

As of 2017, blended biodiesel fuels (especially B5, B8, and B20) are regularly used in many heavy-duty vehicles, especially transit buses in US cities. Characterization of exhaust emissions showed significant emission reductions compared to regular diesel.^[4]

Material compatibility

• Plastics: High-density polyethylene (HDPE) is compatible but polyvinyl chloride (PVC) is slowly degraded.^[7] Polystyrene is dissolved on contact with biodiesel.
• Metals: Biodiesel (like methanol) has an effect on copper-based materials (e.g. brass), and it also affects zinc, tin, lead, and cast iron.^[7] Stainless steels (316 and 304) and aluminum are unaffected.
• Rubber: Biodiesel also affects types of natural rubbers found in some older engine components. Studies have also found that fluorinated elastomers (FKM) cured with peroxide and base-metal oxides can be degraded when biodiesel loses its stability caused by oxidation. Commonly used synthetic rubbers FKM- GBL-S and FKM- GF-S found in modern vehicles were found to handle biodiesel in all conditions.^[72]

Discover more about Applications related topics

Common rail

Common rail

Common rail direct fuel injection is a direct fuel injection system built around a high-pressure fuel rail feeding solenoid valves, as opposed to a low-pressure fuel pump feeding unit injectors. High-pressure injection delivers power and fuel consumption benefits over earlier lower pressure fuel injection, by injecting fuel as a larger number of smaller droplets, giving a much higher ratio of surface area to volume. This provides improved vaporization from the surface of the fuel droplets, and so more efficient combining of atmospheric oxygen with vaporized fuel delivering more complete combustion.

Solvent

Solvent

A solvent is a substance that dissolves a solute, resulting in a solution. A solvent is usually a liquid but can also be a solid, a gas, or a supercritical fluid. Water is a solvent for polar molecules and the most common solvent used by living things; all the ions and proteins in a cell are dissolved in water within the cell.

Gasket

Gasket

A gasket is a mechanical seal which fills the space between two or more mating surfaces, generally to prevent leakage from or into the joined objects while under compression. It is a deformable material that is used to create a static seal and maintain that seal under various operating conditions in a mechanical assembly.

FKM

FKM

FKM is a family of fluorocarbon-based fluoroelastomer materials defined by ASTM International standard D1418, and ISO standard 1629. It is commonly called fluorine rubber or fluoro-rubber. FKM is an abbreviation of Fluorine Kautschuk Material. All FKMs contain vinylidene fluoride as a monomer. Originally developed by DuPont, FKMs are today also produced by many companies, including: Daikin (Dai-El), 3M (Dyneon), Solvay S.A. (Tecnoflon), HaloPolymer (Elaftor), Gujarat Fluorochemicals (Fluonox), and several Chinese manufacturers. Fluoroelastomers are more expensive than neoprene or nitrile rubber elastomers. They provide additional heat and chemical resistance. FKMs can be divided into different classes on the basis of either their chemical composition, their fluorine content, or their cross-linking mechanism.

Fuel filter

Fuel filter

A fuel filter is a filter used to screens out foreign particles or liquids from the fuel. Most internal combustion engines use a fuel filter, in order to protect the components in the fuel system.

Energy Policy Act of 2005

Energy Policy Act of 2005

The Energy Policy Act of 2005 is a federal law signed by President George W. Bush on August 8, 2005, at Sandia National Laboratories in Albuquerque, New Mexico. The act, described by proponents as an attempt to combat growing energy problems, changed US energy policy by providing tax incentives and loan guarantees for energy production of various types. The most consequential aspect of the law was to greatly increase ethanol production to be blended with gasoline. The law also repealed the Public Utility Holding Company Act of 1935, effective February 2006.

Renewable Transport Fuel Obligation

Renewable Transport Fuel Obligation

The Renewable Transport Fuel Obligation (RTFO) in the United Kingdom is a requirement on transport fuel suppliers to ensure that 5 per cent of all road vehicle fuel is supplied from sustainable renewable sources by 2010. The Government intends to set variable targets for the level of carbon and sustainability performance expected from all transport fuel suppliers claiming certificates for biofuels in the early years of the RTFO.

EN 14214

EN 14214

EN 14214 is a standard published by the European Committee for Standardization that describes the requirements and test methods for FAME - the most common type of biodiesel.

Mount Washington Cog Railway

Mount Washington Cog Railway

The Mount Washington Cog Railway, also known as the Cog, is the world's first mountain-climbing cog railway. The railway climbs Mount Washington in New Hampshire, United States. It uses a Marsh rack system and both steam and biodiesel-powered locomotives to carry tourists to the top of the mountain. Its track is built to a 4 ft 8 in gauge, which is technically a narrow gauge, as it is 1⁄2 inch (13 mm) less than a 4 ft 8+1⁄2 in standard gauge.

Train operating company

Train operating company

A train operating company (TOC) is the term used on the railway system of Great Britain for a railway undertaking operating passenger trains under the collective National Rail brand. TOCs have existed since the privatisation of the network under the Railways Act 1993.

British Rail Class 220

British Rail Class 220

The British Rail Class 220 Voyager is a class of diesel-electric high-speed multiple unit passenger trains built in Belgium by Bombardier Transportation in 2000 and 2001. They were introduced in 2001 to replace the 20-year-old InterCity 125 and almost 40-year-old Class 47-hauled Mark 2 fleets operating on the Cross Country Route. They were initially operated by Virgin CrossCountry and since 2007 have been operated by CrossCountry.

British Royal Train

British Royal Train

The British Royal Train is used to convey senior members of the British royal family and associated staff of the Royal Household around the railway network of Great Britain. It is owned, maintained and operated by DB Cargo UK.

Biodiesel has a number of standards for its quality including European standard EN 14214, ASTM International D6751, and National Standard of Canada CAN/CGSB-3.524.

ASTM D6751 (American Society for Testing and Materials) details standards and specifications for biodiesels blended with middle distillate fuels. This specification standard specifies various test methods to be used in the determination of certain properties for biodiesel blends. Some of the tests mentioned include flash point and kinematic viscosity.[3]

When biodiesel is cooled below a certain point, some of the molecules aggregate and form crystals. The fuel starts to appear cloudy once the crystals become larger than one quarter of the wavelengths of visible light – this is the cloud point (CP). As the fuel is cooled further these crystals become larger. The lowest temperature at which fuel can pass through a 45 micrometre filter is the cold filter plugging point (CFPP).^[73] As biodiesel is cooled further it will gel and then solidify. Within Europe, there are differences in the CFPP requirements between countries. This is reflected in the different national standards of those countries. The temperature at which pure (B100) biodiesel starts to gel varies significantly and depends upon the mix of esters and therefore the feedstock oil used to produce the biodiesel. For example, biodiesel produced from low erucic acid varieties of canola seed (RME) starts to gel at approximately −10 °C (14 °F). Biodiesel produced from beef tallow and palm oil tends to gel at around 16 °C (61 °F) and 13 °C (55 °F) respectively.^[74] There are a number of commercially available additives that will significantly lower the pour point and cold filter plugging point of pure biodiesel. Winter operation is also possible by blending biodiesel with other fuel oils including #2 low sulfur diesel fuel and #1 diesel / kerosene.

Another approach to facilitate the use of biodiesel in cold conditions is by employing a second fuel tank for biodiesel in addition to the standard diesel fuel tank. The second fuel tank can be insulated and a heating coil using engine coolant is run through the tank. The fuel tanks can be switched over when the fuel is sufficiently warm. A similar method can be used to operate diesel vehicles using straight vegetable oil.

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Visible spectrum

Visible spectrum

The visible spectrum is the portion of the electromagnetic spectrum that is visible to the human eye. Electromagnetic radiation in this range of wavelengths is called visible light or simply light. A typical human eye will respond to wavelengths from about 380 to about 750 nanometers. In terms of frequency, this corresponds to a band in the vicinity of 400–790 terahertz. These boundaries are not sharply defined and may vary per individual. Under optimal conditions these limits of human perception can extend to 310 nm (ultraviolet) and 1100 nm. The optical spectrum is sometimes considered to be the same as the visible spectrum, but some authors define the term more broadly, to include the ultraviolet and infrared parts of the electromagnetic spectrum as well.

Cloud point

Cloud point

In liquids, the cloud point is the temperature below which a transparent solution undergoes either a liquid-liquid phase separation to form an emulsion or a liquid-solid phase transition to form either a stable sol or a suspension that settles a precipitate. The cloud point is analogous to the 'dew point' at which a gas-liquid phase transition called condensation occurs in water vapour to form liquid water. When the temperature is below 0 °C, the dew point is called the frost point, as water vapour undergoes gas-solid phase transition called deposition, solidification, or freezing.

Cold filter plugging point

Cold filter plugging point

Cold filter plugging point (CFPP) is the lowest temperature, expressed in degrees Celsius (°C), at which a given volume of diesel type of fuel still passes through a standardized filtration device in a specified time when cooled under certain conditions. This test gives an estimate for the lowest temperature that a fuel will give trouble free flow in certain fuel systems. This is important as in cold temperate countries, a high cold filter plugging point will clog up vehicle engines more easily.

Erucic acid

Erucic acid

Erucic acid is a monounsaturated omega-9 fatty acid, denoted 22:1ω9. It has the chemical formula CH3(CH2)7CH=CH(CH2)11COOH. It is prevalent in wallflower seed and other plants in the family Brassicaceae, with a reported content of 20 to 54% in high erucic acid rapeseed oil and 42% in mustard oil. Erucic acid is also known as cis-13-docosenoic acid and the trans isomer is known as brassidic acid.

Tallow

Tallow

Tallow is a rendered form of beef or mutton fat, primarily made up of triglycerides.

Palm oil

Palm oil

Palm oil is an edible vegetable oil derived from the mesocarp of the fruit of the oil palms. The oil is used in food manufacturing, in beauty products, and as biofuel. Palm oil accounted for about 33% of global oils produced from oil crops in 2014. Palm oils are easier to stabilize and maintain quality of flavor and consistency in processed foods, so are frequently favored by food manufacturers. On average globally, humans consumed 7.7 kg (17 lb) of palm oil per person in 2015. Demand has also increased for other uses, such as cosmetics and biofuels, creating more demand on the supply encouraging the growth of palm oil plantations in tropical countries.

Sulfur

Sulfur

Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula S8. Elemental sulfur is a bright yellow, crystalline solid at room temperature.

Kerosene

Kerosene

Kerosene, paraffin, or lamp oil is a combustible hydrocarbon liquid which is derived from petroleum. It is widely used as a fuel in aviation as well as households. Its name derives from Greek: κηρός (keros) meaning "wax", and was registered as a trademark by Canadian geologist and inventor Abraham Gesner in 1854 before evolving into a generic trademark. It is sometimes spelled kerosine in scientific and industrial usage. The term kerosene is common in much of Argentina, Australia, Canada, India, New Zealand, Nigeria, and the United States, while the term paraffin is used in Chile, eastern Africa, South Africa, Norway, and in the United Kingdom. The term lamp oil, or the equivalent in the local languages, is common in the majority of Asia and the Southeastern United States. Liquid paraffin is a more viscous and highly refined product which is used as a laxative. Paraffin wax is a waxy solid extracted from petroleum.

Thermal insulation

Thermal insulation

Thermal insulation is the reduction of heat transfer between objects in thermal contact or in range of radiative influence. Thermal insulation can be achieved with specially engineered methods or processes, as well as with suitable object shapes and materials.

Heat exchanger

Heat exchanger

A heat exchanger is a system used to transfer heat between a source and a working fluid. Heat exchangers are used in both cooling and heating processes. The fluids may be separated by a solid wall to prevent mixing or they may be in direct contact. They are widely used in space heating, refrigeration, air conditioning, power stations, chemical plants, petrochemical plants, petroleum refineries, natural-gas processing, and sewage treatment. The classic example of a heat exchanger is found in an internal combustion engine in which a circulating fluid known as engine coolant flows through radiator coils and air flows past the coils, which cools the coolant and heats the incoming air. Another example is the heat sink, which is a passive heat exchanger that transfers the heat generated by an electronic or a mechanical device to a fluid medium, often air or a liquid coolant.

Antifreeze

Antifreeze

An antifreeze is an additive which lowers the freezing point of a water-based liquid. An antifreeze mixture is used to achieve freezing-point depression for cold environments. Common antifreezes also increase the boiling point of the liquid, allowing higher coolant temperature. However, all common antifreeze additives also have lower heat capacities than water, and do reduce water's ability to act as a coolant when added to it.

Biodiesel may contain small but problematic quantities of water. Although it is only slightly miscible with water it is hygroscopic.^[75] One of the reasons biodiesel can absorb water is the persistence of mono and diglycerides left over from an incomplete reaction. These molecules can act as an emulsifier, allowing water to mix with the biodiesel. In addition, there may be water that is residual to processing or resulting from storage tank condensation. The presence of water is a problem because:

• Water reduces the heat of fuel combustion, causing smoke, harder starting, and reduced power.
• Water causes corrosion of fuel system components (pumps, fuel lines, etc.)
• Microbes in water cause the paper-element filters in the system to rot and fail, causing failure of the fuel pump due to ingestion of large particles.
• Water freezes to form ice crystals that provide sites for nucleation, accelerating gelling of the fuel.
• Water causes pitting in pistons.

Previously, the amount of water contaminating biodiesel has been difficult to measure by taking samples, since water and oil separate. However, it is now possible to measure the water content using water-in-oil sensors.^[76]

Water contamination is also a potential problem when using certain chemical catalysts involved in the production process, substantially reducing catalytic efficiency of base (high pH) catalysts such as potassium hydroxide. However, the super-critical methanol production methodology, whereby the transesterification process of oil feedstock and methanol is effectuated under high temperature and pressure, has been shown to be largely unaffected by the presence of water contamination during the production phase.

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Hygroscopy

Hygroscopy

Hygroscopy is the phenomenon of attracting and holding water molecules via either absorption or adsorption from the surrounding environment, which is usually at normal or room temperature. If water molecules become suspended among the substance's molecules, adsorbing substances can become physically changed, e.g., changing in volume, boiling point, viscosity or some other physical characteristic or property of the substance. For example, a finely dispersed hygroscopic powder, such as a salt, may become clumpy over time due to collection of moisture from the surrounding environment.

Condensation

Condensation

Condensation is the change of the state of matter from the gas phase into the liquid phase, and is the reverse of vaporization. The word most often refers to the water cycle. It can also be defined as the change in the state of water vapor to liquid water when in contact with a liquid or solid surface or cloud condensation nuclei within the atmosphere. When the transition happens from the gaseous phase into the solid phase directly, the change is called deposition.

Combustion

Combustion

Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion does not always result in fire, because a flame is only visible when substances undergoing combustion vaporize, but when it does, a flame is a characteristic indicator of the reaction. While the activation energy must be overcome to initiate combustion, the heat from a flame may provide enough energy to make the reaction self-sustaining.

Power (physics)

Power (physics)

In physics, power is the amount of energy transferred or converted per unit time. In the International System of Units, the unit of power is the watt, equal to one joule per second. In older works, power is sometimes called activity. Power is a scalar quantity.

Corrosion

Corrosion

Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials by chemical or electrochemical reaction with their environment. Corrosion engineering is the field dedicated to controlling and preventing corrosion.

Nucleation

Nucleation

In thermodynamics, nucleation is the first step in the formation of either a new thermodynamic phase or structure via self-assembly or self-organization within a substance or mixture. Nucleation is typically defined to be the process that determines how long an observer has to wait before the new phase or self-organized structure appears. For example, if a volume of water is cooled below 0 °C, it will tend to freeze into ice, but volumes of water cooled only a few degrees below 0 °C often stay completely free of ice for long periods (supercooling). At these conditions, nucleation of ice is either slow or does not occur at all. However, at lower temperatures nucleation is fast, and ice crystals appear after little or no delay.

Potassium hydroxide

Potassium hydroxide

Potassium hydroxide is an inorganic compound with the formula KOH, and is commonly called caustic potash.

In some countries biodiesel is less expensive than conventional diesel

Global biodiesel production reached 3.8 million tons in 2005. Approximately 85% of biodiesel production came from the European Union.^[77]

Biodiesel is commonly produced by the transesterification of the vegetable oil or animal fat feedstock, and other non-edible raw materials such as frying oil, etc. There are several methods for carrying out this transesterification reaction including the common batch process, heterogeneous catalysts,^[78] supercritical processes, ultrasonic methods, and even microwave methods.

Chemically, transesterified biodiesel comprises a mix of mono-alkyl esters of long chain fatty acids. The most common form uses methanol (converted to sodium methoxide) to produce methyl esters (commonly referred to as Fatty Acid Methyl Ester – FAME) as it is the cheapest alcohol available, though ethanol can be used to produce an ethyl ester (commonly referred to as Fatty Acid Ethyl Ester – FAEE) biodiesel and higher alcohols such as isopropanol and butanol have also been used. Using alcohols of higher molecular weights improves the cold flow properties of the resulting ester, at the cost of a less efficient transesterification reaction. A lipid transesterification production process is used to convert the base oil to the desired esters. Any free fatty acids (FFAs) in the base oil are either converted to soap and removed from the process, or they are esterified (yielding more biodiesel) using an acidic catalyst. After this processing, unlike straight vegetable oil, biodiesel has combustion properties very similar to those of petroleum diesel, and can replace it in most current uses.

The methanol used in most biodiesel production processes is made using fossil fuel inputs. However, there are sources of renewable methanol made using carbon dioxide or biomass as feedstock, making their production processes free of fossil fuels.^[79]

A by-product of the transesterification process is the production of glycerol. For every 1 tonne of biodiesel that is manufactured, 100 kg of glycerol are produced. Originally, there was a valuable market for the glycerol, which assisted the economics of the process as a whole. However, with the increase in global biodiesel production, the market price for this crude glycerol (containing 20% water and catalyst residues) has crashed. Research is being conducted globally to use this glycerol as a chemical building block (see chemical intermediate under Wikipedia article "Glycerol"). One initiative in the UK is The Glycerol Challenge.^[80]

Usually this crude glycerol has to be purified, typically by performing vacuum distillation. This is rather energy intensive. The refined glycerol (98%+ purity) can then be utilised directly, or converted into other products. The following announcements were made in 2007: A joint venture of Ashland Inc. and Cargill announced plans to make propylene glycol in Europe from glycerol^[81] and Dow Chemical announced similar plans for North America.^[82] Dow also plans to build a plant in China to make epichlorhydrin from glycerol.^[83] Epichlorhydrin is a raw material for epoxy resins.

Production levels

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In 2007, biodiesel production capacity was growing rapidly, with an average annual growth rate from 2002 to 2006 of over 40%.^[84] For the year 2006, the latest for which actual production figures could be obtained, total world biodiesel production was about 5–6 million tonnes, with 4.9 million tonnes processed in Europe (of which 2.7 million tonnes was from Germany) and most of the rest from the US. In 2008 production in Europe alone had risen to 7.8 million tonnes.^[85] In July 2009, a duty was added to American imported biodiesel in the European Union in order to balance the competition from European, especially German producers.^[86][87] The capacity for 2008 in Europe totalled 16 million tonnes. This compares with a total demand for diesel in the US and Europe of approximately 490 million tonnes (147 billion gallons).^[88] Total world production of vegetable oil for all purposes in 2005–06 was about 110 million tonnes, with about 34 million tonnes each of palm oil and soybean oil.^[89] As of 2018, Indonesia is the world's top supplier of palmoil-based biofuel with annual production of 3.5 million tons,^[90][91] and expected to export about 1 million tonnes of biodiesel.^[92]

US biodiesel production in 2011 brought the industry to a new milestone. Under the EPA Renewable Fuel Standard, targets have been implemented for the biodiesel production plants in order to monitor and document production levels in comparison to total demand. According to the year-end data released by the EPA, biodiesel production in 2011 reached more than 1 billion gallons. This production number far exceeded the 800 million gallon target set by the EPA. The projected production for 2020 is nearly 12 billion gallons.^[93]

Biodiesel feedstocks

A variety of oils can be used to produce biodiesel. These include:

• Virgin oil feedstock – rapeseed and soybean oils are most commonly used, soybean oil ^[4] accounting for about half of U.S. production.^[94] It also can be obtained from Pongamia, field pennycress and jatropha and other crops such as mustard, jojoba, flax, sunflower, palm oil, coconut and hemp (see list of vegetable oils for biofuel for more information);
• Waste vegetable oil (WVO);
• Animal fats including tallow, lard, yellow grease, chicken fat,^[95] and the by-products of the production of Omega-3 fatty acids from fish oil.
• Algae, which can be grown using waste materials such as sewage^[96] and without displacing land currently used for food production.
• Oil from halophytes such as Salicornia bigelovii, which can be grown using saltwater in coastal areas where conventional crops cannot be grown, with yields equal to the yields of soybeans and other oilseeds grown using freshwater irrigation^[97]
• Sewage Sludge – The sewage-to-biofuel field is attracting interest from major companies like Waste Management and startups like InfoSpi, which are betting that renewable sewage biodiesel can become competitive with petroleum diesel on price.^[98]

Many advocates suggest that waste vegetable oil is the best source of oil to produce biodiesel, but since the available supply is drastically less than the amount of petroleum-based fuel that is burned for transportation and home heating in the world, this local solution could not scale to the current rate of consumption.

Animal fats are a by-product of meat production and cooking. Although it would not be efficient to raise animals (or catch fish) simply for their fat, use of the by-product adds value to the livestock industry (hogs, cattle, poultry). Today, multi-feedstock biodiesel facilities are producing high quality animal-fat based biodiesel.^[2][1] Currently, a 5-million dollar plant is being built in the US, with the intent of producing 11.4 million litres (3 million gallons) biodiesel from some of the estimated 1 billion kg (2.2 billion pounds) of chicken fat^[99] produced annually at the local Tyson poultry plant.^[95] Similarly, some small-scale biodiesel factories use waste fish oil as feedstock.^[100][101] An EU-funded project (ENERFISH) suggests that at a Vietnamese plant to produce biodiesel from catfish (basa, also known as pangasius), an output of 13 tons/day of biodiesel can be produced from 81 tons of fish waste (in turn resulting from 130 tons of fish). This project utilises the biodiesel to fuel a CHP unit in the fish processing plant, mainly to power the fish freezing plant.^[102]

Quantity of feedstocks required

Current worldwide production of vegetable oil and animal fat is not sufficient to replace liquid fossil fuel use. Furthermore, some object to the vast amount of farming and the resulting fertilization, pesticide use, and land use conversion that would be needed to produce the additional vegetable oil.^[103] The advantages of algae are that it can be grown on non-arable land such as deserts or in marine environments, and the potential oil yields are much higher than from plants.

Yield

Feedstock yield efficiency per unit area affects the feasibility of ramping up production to the huge industrial levels required to power a significant percentage of vehicles.

Algae fuel yields have not yet been accurately determined, but DOE is reported as saying that algae yield 30 times more energy per acre than land crops such as soybeans.^[105] Yields of 36 tonnes/hectare are considered practical by Ami Ben-Amotz of the Institute of Oceanography in Haifa, who has been farming Algae commercially for over 20 years.^[106]

Jatropha has been cited as a high-yield source of biodiesel but yields are highly dependent on climatic and soil conditions. The estimates at the low end put the yield at about 200 US gal/acre (1.5-2 tonnes per hectare) per crop; in more favorable climates two or more crops per year have been achieved.^[107] It is grown in the Philippines, Mali and India, is drought-resistant, and can share space with other cash crops such as coffee, sugar, fruits and vegetables.^[108] It is well-suited to semi-arid lands and can contribute to slow down desertification, according to its advocates.^[109]

Efficiency and economic arguments

Pure biodiesel (B-100) made from soybeans

Transitioning fully to biofuels could require immense tracts of land if traditional food crops are used (although non food crops can be utilized). The problem would be especially severe for nations with large economies, since energy consumption scales with economic output.^[110]

For third world countries, biodiesel sources that use marginal land could make more sense; e.g., pongam oiltree nuts grown along roads or jatropha grown along rail lines.^[111]

In tropical regions, such as Malaysia and Indonesia, plants that produce palm oil are being planted at a rapid pace to supply growing biodiesel demand in Europe and other markets. Scientists have shown that the removal of rainforest for palm plantations is not ecologically sound since the expansion of oil palm plantations poses a threat to natural rainforest and biodiversity.^[112]

It has been estimated in Germany that palm oil diesel has less than one third of the production costs of rapeseed biodiesel.^[113]

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Biodiesel production

Biodiesel production

Biodiesel production is the process of producing the biofuel, biodiesel, through the chemical reactions of transesterification and esterification. This involves vegetable or animal fats and oils being reacted with short-chain alcohols. The alcohols used should be of low molecular weight. Ethanol is the most used because of its low cost, however, greater conversions into biodiesel can be reached using methanol. Although the transesterification reaction can be catalyzed by either acids or bases, the base-catalyzed reaction is more common. This path has lower reaction times and catalyst cost than those acid catalysis. However, alkaline catalysis has the disadvantage of high sensitivity to both water and free fatty acids present in the oils.

Transesterification

Transesterification

Transesterification is the process of exchanging the organic functional group R″ of an ester with the organic group R' of an alcohol. These reactions are often catalyzed by the addition of an acid or base catalyst. The reaction can also be accomplished with the help of other enzymes, particularly lipases.

Fatty acid

Fatty acid

In chemistry, particularly in biochemistry, a fatty acid is a carboxylic acid with an aliphatic chain, which is either saturated or unsaturated. Most naturally occurring fatty acids have an unbranched chain of an even number of carbon atoms, from 4 to 28. Fatty acids are a major component of the lipids in some species such as microalgae but in some other organisms are not found in their standalone form, but instead exist as three main classes of esters: triglycerides, phospholipids, and cholesteryl esters. In any of these forms, fatty acids are both important dietary sources of fuel for animals and important structural components for cells.

Methanol

Methanol

Methanol (also called methyl alcohol and wood spirit, amongst other names) is an organic chemical and the simplest aliphatic alcohol, with the formula CH3OH (a methyl group linked to a hydroxyl group, often abbreviated as MeOH). It is a light, volatile, colourless, flammable liquid with a distinctive alcoholic odour similar to that of ethanol (potable alcohol). Methanol acquired the name wood alcohol because it was once produced chiefly by the destructive distillation of wood. Today, methanol is mainly produced industrially by hydrogenation of carbon monoxide.

Fatty acid methyl ester

Fatty acid methyl ester

Fatty acid methyl esters (FAME) are a type of fatty acid ester that are derived by transesterification of fats with methanol. The molecules in biodiesel are primarily FAME, usually obtained from vegetable oils by transesterification. They are used to produce detergents and biodiesel. FAME are typically produced by an alkali-catalyzed reaction between fats and methanol in the presence of base such as sodium hydroxide, sodium methoxide or potassium hydroxide. One of the reasons for FAME use in biodiesel instead of free fatty acids is to nullify any corrosion that free fatty acids would cause to the metals of engines, production facilities and so forth. Free fatty acids are only mildly acidic, but in time can cause cumulative corrosion unlike their esters. As an improved quality, FAMEs also usually have about 12-15 units higher cetane number than their unesterified counterparts.

Ethanol

Ethanol

Ethanol is an organic compound. It is an alcohol with the chemical formula C2H6O. Its formula can also be written as CH3−CH2−OH or C2H5OH. Ethanol is a volatile, flammable, colorless liquid with a characteristic wine-like odor and pungent taste. It is a psychoactive recreational drug, and the active ingredient in alcoholic drinks.

Lipid

Lipid

Lipids are a broad group of naturally-occurring molecules which includes fats, waxes, sterols, fat-soluble vitamins, monoglycerides, diglycerides, phospholipids, and others. The functions of lipids include storing energy, signaling, and acting as structural components of cell membranes. Lipids have applications in the cosmetic and food industries, and in nanotechnology.

Saponification

Saponification

Saponification is a process of converting esters into soaps and alcohols by the action of aqueous alkali. Soaps are salts of fatty acids, which in turn are carboxylic acids with long carbon chains. Sodium stearate is a typical soap.

Carbon Recycling International

Carbon Recycling International

Carbon Recycling International (CRI) is an Icelandic limited liability company which has developed a technology designed to produce renewable methanol from carbon dioxide and hydrogen, using water electrolysis or, alternatively, hydrogen captured from industrial waste gases. The technology is trademarked by CRI as Emissions-to-Liquids (ETL) and the renewable methanol produced by CRI is trademarked as Vulcanol. In 2011 CRI became the first company to produce and sell liquid renewable transport fuel produced using only carbon dioxide, water and electricity from renewable sources.

Glycerol

Glycerol

Glycerol, also called glycerine in British English and glycerin in American English, is a simple triol compound. It is a colorless, odorless, viscous liquid that is sweet-tasting and non-toxic. The glycerol backbone is found in lipids known as glycerides. Because it has antimicrobial and antiviral properties, it is widely used in wound and burn treatments approved by the U.S. Food and Drug Administration. Conversely, it is also used as a bacterial culture medium. Its presence in blood can be used as an effective marker to measure liver disease. It is also widely used as a sweetener in the food industry and as a humectant in pharmaceutical formulations. Because of its three hydroxyl groups, glycerol is miscible with water and is hygroscopic in nature.

Cargill

Cargill

Cargill, Incorporated, is a privately held American global food corporation based in Minnetonka, Minnesota, and incorporated in Wilmington, Delaware. Founded in 1865, it is the largest privately held corporation in the United States in terms of revenue. If it were a public company, it would rank, as of 2015, number 15 on the Fortune 500, behind McKesson and ahead of AT&T. Cargill has frequently been the subject of criticism related to the environment, human rights, finance, and other ethical considerations.

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Multiple economic studies have been performed regarding the economic impact of biodiesel production. One study, commissioned by the National Biodiesel Board, reported the production of biodiesel supported more than 64,000 jobs.^[93] The growth in biodiesel also helps significantly increase GDP. In 2011, biodiesel created more than $3 billion in GDP. Judging by the continued growth in the Renewable Fuel Standard and the extension of the biodiesel tax incentive, the number of jobs can increase to 50,725, $2.7 billion in income, and reaching $5 billion in GDP by 2012 and 2013.^[114]

One of the main drivers for adoption of biodiesel is energy security. This means that a nation's dependence on oil is reduced, and substituted with use of locally available sources, such as coal, gas, or renewable sources. Thus a country can benefit from adoption of biofuels, without a reduction in greenhouse gas emissions. While the total energy balance is debated, it is clear that the dependence on oil is reduced. One example is the energy used to manufacture fertilizers, which could come from a variety of sources other than petroleum. The US National Renewable Energy Laboratory (NREL) states that energy security is the number one driving force behind the US biofuels programme,^[115] and a White House "Energy Security for the 21st Century" paper makes it clear that energy security is a major reason for promoting biodiesel.^[116] The former EU commission president, Jose Manuel Barroso, speaking at a recent EU biofuels conference, stressed that properly managed biofuels have the potential to reinforce the EU's security of supply through diversification of energy sources.^[117]

Many countries around the world are involved in the growing use and production of biofuels, such as biodiesel, as an alternative energy source to fossil fuels and oil. To foster the biofuel industry, governments have implemented legislations and laws as incentives to reduce oil dependency and to increase the use of renewable energies.^[118] Many countries have their own independent policies regarding the taxation and rebate of biodiesel use, import, and production.

Canada

It was required by the Canadian Environmental Protection Act Bill C-33 that by 2010, gasoline contained 5% renewable content and that by 2013, diesel and heating oil contained 2% renewable content.^[118] The EcoENERGY for Biofuels Program subsidized the production of biodiesel, among other biofuels, via an incentive rate of CAN$0.20 per liter from 2008 to 2010. A decrease of $0.04 will be applied every year following, until the incentive rate reaches $0.06 in 2016. Individual provinces also have specific legislative measures in regards to biofuel use and production.^[119]

United States

The Volumetric Ethanol Excise Tax Credit (VEETC) was the main source of financial support for biofuels, but was scheduled to expire in 2010. Through this act, biodiesel production guaranteed a tax credit of US$1 per gallon produced from virgin oils, and $0.50 per gallon made from recycled oils.^[120] Currently soybean oil is being used to produce soybean biodiesel for many commercial purposes such as blending fuel for transportation sectors.^[4]

European Union

The European Union is the greatest producer of biodiesel, with France and Germany being the top producers. To increase the use of biodiesel, there are policies requiring the blending of biodiesel into fuels, including penalties if those rates are not reached. In France, the goal was to reach 10% integration but plans for that stopped in 2010.^[118] As an incentive for the European Union countries to continue the production of the biofuel, there are tax rebates for specific quotas of biofuel produced. In Germany, the minimum percentage of biodiesel in transport diesel is set at 7% so called "B7".

Malaysia

Malaysia plans to implement its nationwide adoption of the B20 palm oil biofuel programme by the end of 2022. The mandate to manufacture biofuel with a 20% palm oil component - known as B20 - for the transport sector was first rolled out in January 2020 but faced delays due to movement curbs imposed to contain coronavirus outbreaks.^[121]

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France

France

France, officially the French Republic, is a country located primarily in Western Europe. It also includes overseas regions and territories in the Americas and the Atlantic, Pacific and Indian Oceans, giving it one of the largest discontiguous exclusive economic zones in the world. Its metropolitan area extends from the Rhine to the Atlantic Ocean and from the Mediterranean Sea to the English Channel and the North Sea; overseas territories include French Guiana in South America, Saint Pierre and Miquelon in the North Atlantic, the French West Indies, and many islands in Oceania and the Indian Ocean. Its eighteen integral regions span a combined area of 643,801 km2 (248,573 sq mi) and had a total population of over 68 million as of January 2023. France is a unitary semi-presidential republic with its capital in Paris, the country's largest city and main cultural and commercial centre; other major urban areas include Marseille, Lyon, Toulouse, Lille, Bordeaux, and Nice.

Germany

Germany

Germany, officially the Federal Republic of Germany, is a country in Central Europe. It is the second-most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated between the Baltic and North seas to the north, and the Alps to the south; it covers an area of 357,022 square kilometres (137,847 sq mi), with a population of over 84 million within its 16 constituent states. Germany borders Denmark to the north, Poland and the Czech Republic to the east, Austria and Switzerland to the south, and France, Luxembourg, Belgium, and the Netherlands to the west. The nation's capital and most populous city is Berlin and its main financial centre is Frankfurt; the largest urban area is the Ruhr.

Malaysia

Malaysia

Malaysia is a country in Southeast Asia. The federal constitutional monarchy consists of thirteen states and three federal territories, separated by the South China Sea into two regions: Peninsular Malaysia and Borneo's East Malaysia. Peninsular Malaysia shares a land and maritime border with Thailand and maritime borders with Singapore, Vietnam, and Indonesia. East Malaysia shares land and maritime borders with Brunei and Indonesia, and a maritime border with the Philippines and Vietnam. Kuala Lumpur is the national capital, the country's largest city, and the seat of the legislative branch of the federal government. Putrajaya is the administrative center, which represents the seat of both the executive branch and the judicial branch of the federal government. With a population of over 32 million, Malaysia is the world's 45th-most populous country. The southernmost point of continental Eurasia is in Tanjung Piai. Located in the tropics, Malaysia is one of 17 megadiverse countries, home to numerous endemic species.

This section's factual accuracy may be compromised due to out-of-date information. Please help update this article to reflect recent events or newly available information. (October 2022)

Deforestation in Indonesia, to make way for an oil palm plantation.

The surge of interest in biodiesels has highlighted a number of environmental effects associated with its use. These potentially include reductions in greenhouse gas emissions,^[122] deforestation, pollution and the rate of biodegradation.

According to the Renewable Fuel Standards Program Regulatory Impact Analysis, released by the Environmental Protection Agency (EPA) of the United States in February 2010, biodiesel from soy oil results, on average, in a 57% reduction in greenhouse gases compared to petroleum diesel, and biodiesel produced from waste grease results in an 86% reduction. See chapter 2.6 of the EPA report for more detailed information.

However, environmental organizations, for example, Rainforest Rescue^[123] and Greenpeace,^[124] criticize the cultivation of plants used for biodiesel production, e.g., oil palms, soybeans and sugar cane. The deforestation of rainforests exacerbates climate change and sensitive ecosystems are destroyed to clear land for oil palm, soybean and sugar cane plantations. Moreover, that biofuels contribute to world hunger, since arable land is no longer used for growing foods. The Environmental Protection Agency published data in January 2012, showing that biofuels made from palm oil will not count towards the renewable fuels mandate of the United States as they are not climate-friendly.^[125] Environmentalists welcome the conclusion because the growth of oil palm plantations has driven tropical deforestation, for example, in Indonesia and Malaysia.^[125][126]

Indonesia produces biodiesel primarily from palm oil. Since agricultural land is limited, in order to plant monocultures of oil palms, land used for other cultivations or the tropical forest need to be cleared. A major environmental threat is then the destruction of rainforests in Indonesia.^[127]

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Environmental impact of biodiesel

Environmental impact of biodiesel

The environmental impact of biodiesel is diverse and not clearcut. An often mentioned incentive for using biodiesel is its capacity to lower greenhouse gas emissions compared to those of fossil fuels. Whether this is true or not depends on many factors.

Deforestation in Indonesia

Deforestation in Indonesia

Deforestation in Indonesia involves the long-term loss of forests and foliage across much of the country; it has had massive environmental and social impacts. Indonesia is home to some of the most biologically diverse forests in the world and ranks third in number of species behind Brazil and the Democratic Republic of Congo.

List of environmental issues

List of environmental issues

This is an alphabetical list of environmental issues, harmful aspects of human activity on the biophysical environment. They are loosely divided into causes, effects and mitigation, noting that effects are interconnected and can cause new effects.

Greenhouse gas emissions

Greenhouse gas emissions

Greenhouse gas emissions from human activities strengthen the greenhouse effect, contributing to climate change. Most is carbon dioxide from burning fossil fuels: coal, oil, and natural gas. The largest emitters include coal in China and large oil and gas companies. Human-caused emissions have increased atmospheric carbon dioxide by about 50% over pre-industrial levels. The growing levels of emissions have varied, but have been consistent among all greenhouse gases (GHGs). Emissions in the 2010s averaged 56 billion tons a year, higher than any decade before.

Deforestation

Deforestation

Deforestation or forest clearance is the removal of a forest or stand of trees from land that is then converted to non-forest use. Deforestation can involve conversion of forest land to farms, ranches, or urban use. The most concentrated deforestation occurs in tropical rainforests. About 31% of Earth's land surface is covered by forests at present. This is one-third less than the forest cover before the expansion of agriculture, a half of that loss occurring in the last century. Between 15 million to 18 million hectares of forest, an area the size of Bangladesh, are destroyed every year. On average 2,400 trees are cut down each minute.

Biodegradation

Biodegradation

Biodegradation is the breakdown of organic matter by microorganisms, such as bacteria and fungi. It is generally assumed to be a natural process, which differentiates it from composting. Composting is a human-driven process in which biodegradation occurs under a specific set of circumstances.

Rettet den Regenwald

Rettet den Regenwald

Rainforest Rescue is a non-governmental environmental organization with head office in Germany which advocates the preservation of rainforests at global level. It is a politically independent organization that defends the inhabitants of the tropical rainforests and their living spaces. The work of the organization consists in launching petitions on its website and collecting donations for concrete projects in the affected tropical areas. The protest actions mainly deal with ecologic and social problems caused by the trade of tropical timber, gold mining, the expansion of industrial-scale monocultures and land conflicts with indigenous populations.

Greenpeace

Greenpeace

Greenpeace is an independent global campaigning network, founded in Canada in 1971 by Irving Stowe and Dorothy Stowe, immigrant environmental activists from the United States. Greenpeace states its goal is to "ensure the ability of the Earth to nurture life in all its diversity" and focuses its campaigning on worldwide issues such as climate change, deforestation, overfishing, commercial whaling, genetic engineering, and anti-nuclear issues. It uses direct action, lobbying, research, and ecotage to achieve its goals.

Indonesia

Indonesia

Indonesia, officially the Republic of Indonesia, is a country in Southeast Asia and Oceania between the Indian and Pacific oceans. It consists of over 17,000 islands, including Sumatra, Java, Sulawesi, and parts of Borneo and New Guinea. Indonesia is the world's largest archipelagic state and the 14th-largest country by area, at 1,904,569 square kilometres. With over 275 million people, Indonesia is the world's fourth-most populous country and the most populous Muslim-majority country. Java, the world's most populous island, is home to more than half of the country's population.

Palm oil

Palm oil

Palm oil is an edible vegetable oil derived from the mesocarp of the fruit of the oil palms. The oil is used in food manufacturing, in beauty products, and as biofuel. Palm oil accounted for about 33% of global oils produced from oil crops in 2014. Palm oils are easier to stabilize and maintain quality of flavor and consistency in processed foods, so are frequently favored by food manufacturers. On average globally, humans consumed 7.7 kg (17 lb) of palm oil per person in 2015. Demand has also increased for other uses, such as cosmetics and biofuels, creating more demand on the supply encouraging the growth of palm oil plantations in tropical countries.

Monoculture

Monoculture

In agriculture, monoculture is the practice of growing one crop species in a field at a time. Monoculture is widely used in intensive farming and in organic farming: both a 1,000-hectare cornfield and a 10-ha field of organic kale are monocultures. Monoculture of crops has allowed farmers to increase efficiency in planting, managing, and harvesting, mainly by facilitating the use of machinery in these operations, but monocultures can also increase the risk of diseases or pest outbreaks. Diversity can be added both in time, as with a crop rotation or sequence, or in space, with a polyculture or intercropping.

Elaeis

Elaeis

Elaeis is a genus of palms containing two species, called oil palms. They are used in commercial agriculture in the production of palm oil. The African oil palm E. guineensis is the principal source of palm oil. It is native to west and southwest Africa, occurring between Angola and Gambia. The American oil palm E. oleifera is native to tropical Central and South America, and is used locally for oil production.

Up to 40% of corn produced in the United States is used to make ethanol,^[128] and worldwide 10% of all grain is turned into biofuel.^[129] A 50% reduction in grain used for biofuels in the US and Europe would replace all of Ukraine's grain exports.^[130]

In some poor countries the rising price of vegetable oil is causing problems.^[131][132] Some propose that fuel only be made from non-edible vegetable oils such as camelina, jatropha or seashore mallow^[133] which can thrive on marginal agricultural land where many trees and crops will not grow, or would produce only low yields.

Others argue that the problem is more fundamental. Farmers may switch from producing food crops to producing biofuel crops to make more money, even if the new crops are not edible.^[134][135] The law of supply and demand predicts that if fewer farmers are producing food the price of food will rise. It may take some time, as farmers can take some time to change which things they are growing, but increasing demand for first generation biofuels is likely to result in price increases for many kinds of food. Some have pointed out that there are poor farmers and poor countries who are making more money because of the higher price of vegetable oil.^[136]

Biodiesel from sea algae would not necessarily displace terrestrial land currently used for food production and new algaculture jobs could be created.

By comparison it should be mentioned that the production of biogas utilizes agricultural waste to generate a biofuel known as biogas, and also produces compost, thereby enhancing agriculture, sustainability and food production.

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Food vs. fuel

Food vs. fuel

Food versus fuel is the dilemma regarding the risk of diverting farmland or crops for biofuels production to the detriment of the food supply. The biofuel and food price debate involves wide-ranging views, and is a long-standing, controversial one in the literature. There is disagreement about the significance of the issue, what is causing it, and what can or should be done to remedy the situation. This complexity and uncertainty is due to the large number of impacts and feedback loops that can positively or negatively affect the price system. Moreover, the relative strengths of these positive and negative impacts vary in the short and long terms, and involve delayed effects. The academic side of the debate is also blurred by the use of different economic models and competing forms of statistical analysis.

Ukraine

Ukraine

Ukraine is a country in Eastern Europe. It is the second-largest European country after Russia, which it borders to the east and northeast. Ukraine covers approximately 600,000 square kilometres (230,000 sq mi). Prior to the ongoing Russian invasion, it was the eighth-most populous country in Europe, with a population of around 41 million people. On 1 January 2023, the United Nations estimated the Ukrainian population to be 34.1 million, with record low birth rates. It is also bordered by Belarus to the north; by Poland, Slovakia, and Hungary to the west; and by Romania and Moldova to the southwest; with a coastline along the Black Sea and the Sea of Azov to the south and southeast. Kyiv is the nation's capital and largest city. Ukraine's state language is Ukrainian; Russian is also widely spoken, especially in the east and south.

Camelina

Camelina

Camelina is a genus within the flowering plant family Brassicaceae. The Camelina species, commonly known as false flax, are native to Mediterranean regions of Europe and Asia. Most species of this genus have been little studied, with the exception of Camelina sativa, historically cultivated as an oil plant. Heinrich Johann Nepomuk von Crantz was the first botanist to use the genus Camelina in his classification works in 1762. As a way to reduce fossil fuel emissions, the US Navy tested a 50-50 mix of jet aviation fuel and biofuel derived from camelina seeds in 2010. A study published in December 2016 explained that the current low price of conventional kerosene-based jet fuel makes it cost-prohibitive for commercial airlines to use camelina-based jet fuel. The study said substantial government intervention would be one way to create a market for camelina, by combining 9 percent government subsidy on camelina crop production, with 9 percent tax on the conventional fuel.

Jatropha

Jatropha

Jatropha is a genus of flowering plants in the spurge family, Euphorbiaceae. The name is derived from the Greek words ἰατρός (iatros), meaning "physician", and τροφή (trophe), meaning "nutrition", hence the common name physic nut. Another common name is nettlespurge. It contains approximately 170 species of succulent plants, shrubs and trees. Most of these are native to the Americas, with 66 species found in the Old World. Plants produce separate male and female flowers. As with many members of the family Euphorbiaceae, Jatropha contains compounds that are highly toxic. Jatropha species have traditionally been used in basketmaking, tanning and dye production. In the 2000s, one species, Jatropha curcas, generated interest as an oil crop for biodiesel production and also medicinal importance when used as lamp oil; native Mexicans in the Veracruz area developed by selective breeding a Jatropha curcas variant lacking the toxic compounds, yielding a better income when used as source for biodiesel, because of its edible byproduct. Toxicity may return if edible Jatropha is pollinated by toxic types.

Algaculture

Algaculture

Algaculture is a form of aquaculture involving the farming of species of algae.

Biogas

Biogas

Biogas is a mixture of gases, primarily consisting of methane, carbon dioxide and hydrogen sulphide, produced from raw materials such as agricultural waste, manure, municipal waste, plant material, sewage, green waste, wastewater, and food waste. It is a renewable energy source.

Biofuel

Biofuel

Biofuel is a fuel that is produced over a short time span from biomass, rather than by the very slow natural processes involved in the formation of fossil fuels, such as oil. Biofuel can be produced from plants or from agricultural, domestic or industrial biowaste. The climate change mitigation potential of biofuel varies considerably, from emission levels comparable to fossil fuels in some scenarios to negative emissions in others. Biofuels are mostly used for transportation, but can also be used for heating and electricity. Biofuels are regarded as a renewable energy source.

Compost

Compost

Compost is a mixture of ingredients used as plant fertilizer and to improve soil's physical, chemical, and biological properties. It is commonly prepared by decomposing plant and food waste, recycling organic materials, and manure. The resulting mixture is rich in plant nutrients and beneficial organisms, such as bacteria, protozoa, nematodes, and fungi. Compost improves soil fertility in gardens, landscaping, horticulture, urban agriculture, and organic farming, reducing dependency on commercial chemical fertilizers. The benefits of compost include providing nutrients to crops as fertilizer, acting as a soil conditioner, increasing the humus or humic acid contents of the soil, and introducing beneficial microbes that help to suppress pathogens in the soil and reduce soil-borne diseases.

There was research into finding more suitable crops and improving oil yield. Other sources are possible including human fecal matter, with Ghana building its first "fecal sludge-fed biodiesel plant."^[137]

Specially bred mustard varieties can produce reasonably high oil yields and are very useful in crop rotation with cereals, and have the added benefit that the meal leftover after the oil has been pressed out can act as an effective and biodegradable pesticide.^[138]

The NFESC, with Santa Barbara-based Biodiesel Industries is working to develop biodiesel technologies for the US navy and military, one of the largest diesel fuel users in the world.^[139]

A group of Spanish developers working for a company called Ecofasa announced a new biofuel made from trash. The fuel is created from general urban waste which is treated by bacteria to produce fatty acids, which can be used to make biodiesel.^[140]

Another approach that does not require the use of chemical for the production involves the use of genetically modified microbes.^[141][142]

Algal biodiesel

From 1978 to 1996, the U.S. NREL experimented with using algae as a biodiesel source in the "Aquatic Species Program".^[115] A self-published article by Michael Briggs, at the UNH Biodiesel Group, offers estimates for the realistic replacement of all vehicular fuel with biodiesel by utilizing algae that have a natural oil content greater than 50%, which Briggs suggests can be grown on algae ponds at wastewater treatment plants.^[143] This oil-rich algae can then be extracted from the system and processed into biodiesel, with the dried remainder further reprocessed to create ethanol.

The production of algae to harvest oil for biodiesel has not yet been undertaken on a commercial scale, but feasibility studies have been conducted to arrive at the above yield estimate. In addition to its projected high yield, algaculture — unlike crop-based biofuels — does not entail a decrease in food production, since it requires neither farmland nor fresh water. Many companies are pursuing algae bio-reactors for various purposes, including scaling up biodiesel production to commercial levels.^[144][145] Biodiesel lipids could be extracted from wet algae using a simple and economical reaction in ionic liquids.^[146]

Pongamia

Millettia pinnata, also known as the Pongam Oiltree or Pongamia, is a leguminous, oilseed-bearing tree that has been identified as a candidate for non-edible vegetable oil production.

Pongamia plantations for biodiesel production have a two-fold environmental benefit. The trees both store carbon and produce fuel oil. Pongamia grows on marginal land not fit for food crops and does not require nitrate fertilizers. The oil producing tree has the highest yield of oil producing plant (approximately 40% by weight of the seed is oil) while growing in malnourished soils with high levels of salt. It is becoming a main focus in a number of biodiesel research organizations.^[147] The main advantages of Pongamia are a higher recovery and quality of oil than other crops and no direct competition with food crops. However, growth on marginal land can lead to lower oil yields which could cause competition with food crops for better soil.

Jatropha

Jatropha Biodiesel from DRDO, India.

Several groups in various sectors are conducting research on Jatropha curcas, a poisonous shrub-like tree that produces seeds considered by many to be a viable source of biodiesel feedstock oil.^[148] Much of this research focuses on improving the overall per acre oil yield of Jatropha through advancements in genetics, soil science, and horticultural practices.

SG Biofuels, a San Diego-based Jatropha developer, has used molecular breeding and biotechnology to produce elite hybrid seeds of Jatropha that show significant yield improvements over first generation varieties.^[149] SG Biofuels also claims that additional benefits have arisen from such strains, including improved flowering synchronicity, higher resistance to pests and disease, and increased cold weather tolerance.^[150]

Plant Research International, a department of the Wageningen University and Research Centre in the Netherlands, maintains an ongoing Jatropha Evaluation Project (JEP) that examines the feasibility of large scale Jatropha cultivation through field and laboratory experiments.^[151]

The Center for Sustainable Energy Farming (CfSEF) is a Los Angeles-based non-profit research organization dedicated to Jatropha research in the areas of plant science, agronomy, and horticulture. Successful exploration of these disciplines is projected to increase Jatropha farm production yields by 200–300% in the next ten years.^[152]

FOG from sewage

So-called fats, oils and grease (FOG), recovered from sewage can also be turned into biodiesel.^[153]

Fungi

A group at the Russian Academy of Sciences in Moscow published a paper in 2008, stating that they had isolated large amounts of lipids from single-celled fungi and turned it into biodiesel in an economically efficient manner.^[154]

The recent discovery of a variant of the fungus Gliocladium roseum points toward the production of so-called myco-diesel from cellulose. This organism was recently discovered in the rainforests of northern Patagonia and has the unique capability of converting cellulose into medium length hydrocarbons typically found in diesel fuel.^[155]

Biodiesel from used coffee grounds

Researchers at the University of Nevada, Reno, have successfully produced biodiesel from oil derived from used coffee grounds. Their analysis of the used grounds showed a 10% to 15% oil content (by weight). Once the oil was extracted, it underwent conventional processing into biodiesel. It is estimated that finished biodiesel could be produced for about one US dollar per gallon. Further, it was reported that "the technique is not difficult" and that "there is so much coffee around that several hundred million gallons of biodiesel could potentially be made annually." However, even if all the coffee grounds in the world were used to make fuel, the amount produced would be less than 1 percent of the diesel used in the United States annually. "It won’t solve the world’s energy problem," Dr. Misra said of his work.^[156]

Biodiesel to hydrogen-cell power

A microreactor has been developed to convert biodiesel into hydrogen steam to power fuel cells.^[157]

Steam reforming, also known as fossil fuel reforming is a process which produces hydrogen gas from hydrocarbon fuels, most notably biodiesel due to its efficiency. A **microreactor**, or reformer, is the processing device in which water vapour reacts with the liquid fuel under high temperature and pressure. Under temperatures ranging from 700 – 1100 °C, a nickel-based catalyst enables the production of carbon monoxide and hydrogen:^[158]

Hydrocarbon + H
₂O ⇌ CO + 3H
₂ (Highly endothermic)

Furthermore, a higher yield of hydrogen gas can be harnessed by further oxidizing carbon monoxide to produce more hydrogen and carbon dioxide:

CO + H
₂O → CO₂ + H
₂ (Mildly exothermic)

Safflower oil

As of 2020^[update], researchers at Australia's CSIRO have been studying safflower oil from a specially-bred variety as an engine lubricant, and researchers at Montana State University's Advanced Fuel Centre in the US have been studying the oil's performance in a large diesel engine, with results described as a "game-changer".^[159]

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Ghana

Ghana

Ghana, officially the Republic of Ghana, is a country in West Africa. It abuts the Gulf of Guinea and the Atlantic Ocean to the south, sharing borders with Ivory Coast in the west, Burkina Faso in the north, and Togo in the east. Ghana covers an area of 238,535 km2 (92,099 sq mi), spanning diverse biomes that range from coastal savannas to tropical rainforests. With over 32 million inhabitants, Ghana is the second-most populous country in West Africa, after Nigeria. The capital and largest city is Accra; other major cities are Kumasi, Tamale, and Sekondi-Takoradi.

Crop rotation

Crop rotation

Crop rotation is the practice of growing a series of different types of crops in the same area across a sequence of growing seasons. It reduces reliance on one set of nutrients, pest and weed pressure, and the probability of developing resistant pests and weeds.

Santa Barbara, California

Santa Barbara, California

Santa Barbara is a coastal city in Santa Barbara County, California, of which it is also the county seat. Situated on a south-facing section of coastline, the longest such section on the West Coast of the United States, the city lies between the steeply rising Santa Ynez Mountains and the Pacific Ocean. Santa Barbara's climate is often described as Mediterranean, and the city has been dubbed "The American Riviera". According to the 2020 U.S. Census, the city's population was 88,665.

Algaculture

Algaculture

Algaculture is a form of aquaculture involving the farming of species of algae.

National Renewable Energy Laboratory

National Renewable Energy Laboratory

The National Renewable Energy Laboratory (NREL) in the US specializes in the research and development of renewable energy, energy efficiency, energy systems integration, and sustainable transportation. NREL is a federally funded research and development center sponsored by the Department of Energy and operated by the Alliance for Sustainable Energy, a joint venture between MRIGlobal and Battelle. Located in Golden, Colorado, NREL is home to the National Center for Photovoltaics, the National Bioenergy Center, and the National Wind Technology Center.

Aquatic Species Program

Aquatic Species Program

The Aquatic Species Program was a research program in the United States launched in 1978 by President Jimmy Carter and was funded by the United States Department of Energy, which over the course of nearly two decades looked into the production of energy using algae. Initially, the funding of the Aquatic Species Program was to develop renewable fuel for transportation. Later, the program focused on producing bio-diesel from algae. The research program was discontinued in 1996. The research staff compiled their work and conclusions into a 1998 report.

Motor vehicle

Motor vehicle

A motor vehicle, also known as motorized vehicle or automotive vehicle, is a self-propelled land vehicle, commonly wheeled, that does not operate on rails and is used for the transportation of people or cargo.

Feasibility study

Feasibility study

A feasibility study is an assessment of the practicality of a project or system. A feasibility study aims to objectively and rationally uncover the strengths and weaknesses of an existing business or proposed venture, opportunities and threats present in the natural environment, the resources required to carry through, and ultimately the prospects for success. In its simplest terms, the two criteria to judge feasibility are cost required and value to be attained.

Agriculture

Agriculture

Agriculture encompasses crop and livestock production, aquaculture, fisheries and forestry for food and non-food products. Agriculture was the key development in the rise of sedentary human civilization, whereby farming of domesticated species created food surpluses that enabled people to live in cities. While humans started gathering grains at least 105,000 years ago, nascent farmers only began planting them around 11,500 years ago. Sheep, goats, pigs and cattle were domesticated around 10,000 years ago. Plants were independently cultivated in at least 11 regions of the world. In the twentieth century, industrial agriculture based on large-scale monocultures came to dominate agricultural output.

Fresh water

Fresh water

Fresh water or freshwater is any naturally occurring liquid or frozen water containing low concentrations of dissolved salts and other total dissolved solids. Although the term specifically excludes seawater and brackish water, it does include non-salty mineral-rich waters such as chalybeate springs. Fresh water may encompass frozen and meltwater in ice sheets, ice caps, glaciers, snowfields and icebergs, natural precipitations such as rainfall, snowfall, hail/sleet and graupel, and surface runoffs that form inland bodies of water such as wetlands, ponds, lakes, rivers, streams, as well as groundwater contained in aquifers, subterranean rivers and lakes. Fresh water is the water resource that is of the most and immediate use to humans.

Millettia pinnata

Millettia pinnata

Millettia pinnata is a species of tree in the pea family, Fabaceae, native to eastern and tropical Asia, Australia, and Pacific islands. It is often known by the synonym Pongamia pinnata. Its common names include Indian beech and Pongame oiltree.

Pongamia oil

Pongamia oil

Pongamia oil is derived from the seeds of the Millettia pinnata tree, which is native to tropical and temperate Asia. Millettia pinnata, also known as Pongamia pinnata or Pongamia glabra, is common throughout Asia and thus has many different names in different languages, many of which have come to be used in English to describe the seed oil derived from M. pinnata; Pongamia is often used as the generic name for the tree and is derived from the genus the tree was originally placed in. Other names for this oil include honge oil, kanuga oil, karanja oil, and pungai oil.

Engine wear

Lubricity of fuel plays an important role in wear that occurs in an engine. A diesel engine relies on its fuel to provide lubricity for the metal components that are constantly in contact with each other.^[160] Biodiesel is a much better lubricant compared with fossil petroleum diesel due to the presence of esters. Tests have shown that the addition of a small amount of biodiesel to diesel can significantly increase the lubricity of the fuel in short term.^[161] However, over a longer period of time (2–4 years), studies show that biodiesel loses its lubricity.^[162] This could be because of enhanced corrosion over time due to oxidation of the unsaturated molecules or increased water content in biodiesel from moisture absorption.^[57]

Fuel viscosity

One of the main concerns regarding biodiesel is its viscosity. The viscosity of diesel is 2.5–3.2 cSt at 40 °C and the viscosity of biodiesel made from soybean oil is between 4.2 and 4.6 cSt^[163] The viscosity of diesel must be high enough to provide sufficient lubrication for the engine parts but low enough to flow at operational temperature. High viscosity can plug the fuel filter and injection system in engines.^[163] Vegetable oil is composed of lipids with long chains of hydrocarbons, to reduce its viscosity the lipids are broken down into smaller molecules of esters. This is done by converting vegetable oil and animal fats into alkyl esters using transesterification to reduce their viscosity^[164] Nevertheless, biodiesel viscosity remains higher than that of diesel, and the engine may not be able to use the fuel at low temperatures due to the slow flow through the fuel filter.^[165]

Engine performance

Biodiesel has higher brake-specific fuel consumption compared to diesel, which means more biodiesel fuel consumption is required for the same torque. However, B20 biodiesel blend has been found to provide maximum increase in thermal efficiency, lowest brake-specific energy consumption, and lower harmful emissions.^[4][57][160] The engine performance depends on the properties of the fuel, as well as on combustion, injector pressure and many other factors.^[166] Since there are various blends of biodiesel, that may account for the contradicting reports as regards engine performance.

Exhaust Emissions

The feedstock used to make the biodiesel alters the fuel’s properties by changing the average carbon chain length and number of double bonds present in the fatty acid methyl esters.^[167]